ArticleNature communications2022
Biomimetic non-classical crystallization drives hierarchical structuring of efficient circularly polarized phosphors.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Aliphatic Ligand-Mediated Cu-Cu Distance Tuning Enables Near-Unity Efficient and Color-Tunable Circularly Polarized Luminescent Copper(I) Iodide Clusters.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Calcium ionic replacement in sodium trimetaphosphate particles: a novel strategy for bone tissue engineering.Journal of materials science. Materials in medicine · 2026Article
- Chiral recognition via symmetry-dependent luminescence in zero-dimensional hybrid copper halides.Nature communications · 2025Article
- Strongly photoluminescent and radioluminescent copper(i) iodide hybrid materials made of coordinated ionic chains.Chemical science · 2025Article
- Biobased and biodegradable films exhibiting circularly polarized room temperature phosphorescence.Nature communications · 2024Article
- Processable circularly polarized luminescence material enables flexible stereoscopic 3D imaging.Science advances · 2023Article
- Scale effect of circularly polarized luminescent signal of matter.National science review · 2023Article
- Viewing Aggregation-Induced Emission of Metal Nanoclusters from Design Strategies to Applications.Nanomaterials (Basel, Switzerland) · 2023Review
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Hierarchically structured chiral luminescent materials hold promise for achieving efficient circularly polarized luminescence. However, a feasible chemical route to fabricate hierarchically structured chiral luminescent polycrystals is still elusive because of their complex structures and complicated formation process. We here report a biomimetic non-classical crystallization (BNCC) strategy for preparing efficient hierarchically structured chiral luminescent polycrystals using well-designed highly luminescent homochiral copper(I)-iodide hybrid clusters as basic units for non-classical crystallization. By monitoring the crystallization process, we unravel the BNCC mechanism, which involves crystal nucleation, nanoparticles aggregation, oriented attachment, and mesoscopic transformation processes. We finally obtain the circularly polarized phosphors with both high luminescent efficiency of 32% and high luminescent dissymmetry factor of 1.5 × 10
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