ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Noncovalent Interactions Involving Group 6 in Biological Systems: The Case of Molybdopterin and Tungstopterin Cofactors.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
16 citing papers in PubMed, 57 citations in OpenAlex.
- Comparing Homodimer and Homotrimer Noncovalent Complexes Involving Coinage Metals: A Theoretical Perspective.Chemphyschem : a European journal of chemical physics and physical chemistry · 2026Article
- Substituent-Driven Switch Between Os…O and O…H Interaction and the Emerging Cooperative/Anti-Cooperative Effect in X-Py·OsOChemphyschem : a European journal of chemical physics and physical chemistry · 2026Article
- Metal-Centered Noncovalent Interactions: A Comparative Insight into π-Hole- and σ-Hole-Directed Bonds.Chemphyschem : a European journal of chemical physics and physical chemistry · 2026Article
- Molecular Electrostatic Surface Potential: A Predictive Framework for Noncovalent Interactions and Adsorption Characteristics in Molecular Entities.International journal of molecular sciences · 2026Review
- Is Cobalt Joining the σ‑/π-Hole Crown? Exploring Noncovalent Interactions in Cobalamin.JACS Au · 2025Article
- Interactional Features of (RO)Angewandte Chemie (International ed. in English) · 2025Article
- The Next Frontier in the Study of Noncovalent Bonding: Transition Metals.Molecules (Basel, Switzerland) · 2025Article
- Taxonomy of Chemical Bondings: Opportunities and Challenges.Angewandte Chemie (International ed. in English) · 2025Article
- The Formation of σ-Hole Bonds: A Physical Interpretation.Molecules (Basel, Switzerland) · 2024Article
- Search for Osme Bonds with π Systems as Electron Donors.Molecules (Basel, Switzerland) · 2023Article
- Spodium Bonds Involving Methylmercury and Ethylmercury in Proteins: Insights from X-ray Analysis and Computations.Inorganic chemistry · 2023Article
- An insight into the hydrogen bonding, halogen bonding and chalcogen bonding interactions in manganese(iii) complexes with NRSC advances · 2023Article
- Regium-π Bonds Involving Nucleobases: Theoretical Study and Biological Implications.Inorganic chemistry · 2023Article
- Matere Bonds vs. Multivalent Halogen and Chalcogen Bonds: Three Case Studies.Molecules (Basel, Switzerland) · 2022Article
- Noncovalent Interactions Involving Group 6 in Biological Systems: The Case of Molybdopterin and Tungstopterin Cofactors.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Stereoselective Processes Based on σ-Hole Interactions.Molecules (Basel, Switzerland) · 2022Review
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
In this study we propose to coin the term Wolfium bond (WfB) to refer to a net attractive force (noncovalent interaction) between any element of group 6 and electron donor atoms (neutral molecules or anions) and to differentiate it from a coordination bond (metal-ligand interaction). We provide evidence of the existence of this interaction by inspecting the X-ray crystal structure of proteins containing Molybdopterin and Tungstopterin cofactors from the Protein Data Bank (PDB). The plausible biological role of the interaction as well as its physical nature (antibonding Wf-Ligand orbital involved) are also analyzed by means of ab initio calculations (RI-MP2/def2-TZVP level of theory), Atoms in Molecules (AIM), Natural Bond Orbital (NBO) and Noncovalent Interactions plot (NCIplot) analyses.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.