Evidence map›Paper›PMID 35668065›Full record

ArticleLight, science & applications2022

Electron-phonon coupling-assisted universal red luminescence of o-phenylenediamine-based carbon dots.

Boyang Wang, Zhihong Wei, Laizhi Sui, Jingkun Yu, Baowei Zhang, Xiaoyong Wang, Shengnan Feng, Haoqiang Song, Xue Yong, Yuxi Tian and 2 more

Abstract read
In one paragraph

Article in Light, science & applications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.

0numbers the graph read from it
0cells of the map it votes in
27citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

27 citing papers in PubMed.

  1. Article
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  6. Review
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  8. Article
  9. Precision Nanoconfined Self-Assembly of ACQ Carbon Dots for Enhanced Solid-State Fluorescence.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025
    Article
  10. Surface Engineering Enabled Capacitive Gas-Phase Water Molecule Sensors in Carbon Nanodots.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025
    Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Metal-Doping Strategy for Carbon-Based Sonosensitizer in Sonodynamic Therapy of Glioblastoma.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Article
  16. Article
  17. Article
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  19. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Boyang Wang *Green Catalysis Center, and College of Chemistry, Zhengzhou University, 450000, Zhengzhou, China.
Zhihong Wei *Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, 210023, Nanjing, China.
Laizhi Sui *State Key Lab of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, China.
Jingkun YuGreen Catalysis Center, and College of Chemistry, Zhengzhou University, 450000, Zhengzhou, China.
Baowei ZhangNanochemistry Department, Istituto Italiano di Tecnologia (IIT), via Morego 30, 16163, Genova, Italy.
Xiaoyong WangSchool of Physics, National Laboratory of Solid State Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, 210093, Nanjing, China.ORCID http://orcid.org/0000-0003-1147-0051
Shengnan FengSchool of Physics, National Laboratory of Solid State Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, 210093, Nanjing, China.
Haoqiang SongGreen Catalysis Center, and College of Chemistry, Zhengzhou University, 450000, Zhengzhou, China.
Xue YongDepartment of Chemistry, University of Sheffield, Sheffield, S3 7HF, UK.
Yuxi TianKey Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, 210023, Nanjing, China. tyx@nju.edu.cn.
Bai YangState Key Lab of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 130012, Changchun, China.ORCID http://orcid.org/0000-0003-1939-6423
Siyu LuGreen Catalysis Center, and College of Chemistry, Zhengzhou University, 450000, Zhengzhou, China. sylu2013@zzu.edu.cn.ORCID http://orcid.org/0000-0003-4538-7846

Funding

National Natural Science Foundation of China (National Science Foundation of China) 21905253National Natural Science Foundation of China (National Science Foundation of China) 51973200National Natural Science Foundation of China (National Science Foundation of China) 52122308Natural Science Foundation of Henan Province (Henan Province Natural Science Foundation) 202300410372
6 · The paper itself

Abstract

Due to the complex core-shell structure and variety of surface functional groups, the photoluminescence (PL) mechanism of carbon dots (CDs) remain unclear. o-Phenylenediamine (oPD), as one of the most common precursors for preparing red emissive CDs, has been extensively studied. Interestingly, most of the red emission CDs based on oPD have similar PL emission characteristics. Herein, we prepared six different oPD-based CDs and found that they had almost the same PL emission and absorption spectra after purification. Structural and spectral characterization indicated that they had similar carbon core structures but different surface polymer shells. Furthermore, single-molecule PL spectroscopy confirmed that the multi-modal emission of those CDs originated from the transitions of different vibrational energy levels of the same PL center in the carbon core. In addition, the phenomenon of "spectral splitting" of single-particle CDs was observed at low temperature, which confirmed these oPD-based CDs were unique materials with properties of both organic molecules and quantum dots. Finally, theoretical calculations revealed their potential polymerization mode and carbon core structure. Moreover, we proposed the PL mechanism of red-emitting CDs based on oPD precursors; that is, the carbon core regulates the PL emission, and the polymer shell regulates the PL intensity. Our work resolves the controversy on the PL mechanism of oPD-based red CDs. These findings provide a general guide for the mechanism exploration and structural analysis of other types of CDs.

Identifiers

PMID35668065
PMCPMC9170735

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.