ReviewChemical Society reviews2022
Transformation networks of metal-organic cages controlled by chemical stimuli.
Review in Chemical Society reviews, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 37 papers, 1 of them a synthesis that pooled it.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
37 citing papers in PubMed, 1 synthesis or guideline pooled it.
- Advances in Dynamic/Adaptive Supramolecular Self-Assembly: From Molecular Design to Stimuli-Responsive Control.Macromolecular rapid communications · 2026Pooled it
- HBr-Regulated Smart 2D Copper-Organic Framework for Highly Efficient and Selective Photocatalytic Oxidation.Angewandte Chemie (International ed. in English) · 2026Article
- A Multi-Stimuli Transformational Network of Benzil-Based Pd(II) Assemblies.Angewandte Chemie (International ed. in English) · 2026Article
- TetrahedralJACS Au · 2026Article
- Programming Palladium Cage Geometry through Ligand Redox Modulation.Angewandte Chemie (International ed. in English) · 2026Article
- Light-Driven Proton-Coupled Two-Electron Ligand Reduction Causes the Rearrangement of the Coordination Sphere in Cu(I) 4Journal of the American Chemical Society · 2026Article
- One Coordination Cage, Many Pathways: Multiple Stimuli Drive Reversible Transformations.JACS Au · 2026Article
- Steric Hindrance and Secondary Interactions Govern Reconfiguration Between Two Complex CuAngewandte Chemie (International ed. in English) · 2026Article
- Temperature‑, Concentration‑, and Solvent-DependentJACS Au · 2026Article
- Sequence-encoded layered heteroleptic metalla-[2]catenanes for programmable supramolecular function.Nature communications · 2026Article
- ZrInorganic chemistry · 2025Article
- Structural Interconversions and Guest Binding Properties of Tetrakis(formylpyridine)-BasedJournal of the American Chemical Society · 2025Article
- Steric Restraints in Redox-Active Guanidine Ligands and Their Impact on Coordination Chemistry.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Tuning Connectivity in a Three-Component Assembly of Metal-Organic Cage-Cross-Linked Polymer Networks.Macromolecules · 2025Article
- Novel metallo-supramolecular architectures based on side-pyridine-modified terpyridines: design, self-assembly, and properties.Chemical science · 2025Review
- Heme/NADH Mimics Co-Decorated Allosteric Capsules for Regulating Oxygen Activation and Upregulating Intracellular Methionine Depletion.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- A Dynamic Silver(I) Nanocluster Holds Together a 3 × 3 Self-Assembled Grid.Journal of the American Chemical Society · 2025Article
- Synergistic regulation of metal-organic cage architectures via temperature- and solvent-driven atropisomerism.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Metallacage-crosslinked free-standing supramolecular networks via photo-induced copolymerization for photocatalytic water decontamination.Nature communications · 2025Article
- Self-assembly, interlocking, interconversion and anion-binding catalysis in phenoxazine-based PdNature communications · 2025Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The flexibility of biomolecules enables them to adapt and transform as a result of signals received from the external environment, expressing different functions in different contexts. In similar fashion, coordination cages can undergo stimuli-triggered transformations owing to the dynamic nature of the metal-ligand bonds that hold them together. Different types of stimuli can trigger dynamic reconfiguration of these metal-organic assemblies, to switch on or off desired functionalities. Such adaptable systems are of interest for applications in switchable catalysis, selective molecular recognition or as transformable materials. This review highlights recent advances in the transformation of cages using chemical stimuli, providing a catalogue of reported strategies to transform cages and thus allow the creation of new architectures. Firstly we focus on strategies for transformation through the introduction of new cage components, which trigger reconstitution of the initial set of components. Secondly we summarize conversions triggered by external stimuli such as guests, concentration, solvent or pH, highlighting the adaptation processes that coordination cages can undergo. Finally, systems capable of responding to multiple stimuli are described. Such systems constitute composite chemical networks with the potential for more complex behaviour. We aim to offer new perspectives on how to design transformation networks, in order to shed light on signal-driven transformation processes that lead to the preparation of new functional metal-organic architectures.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.