ArticleJournal of the American Chemical Society2022
Covalent Organic Framework Nanoplates Enable Solution-Processed Crystalline Nanofilms for Photoelectrochemical Hydrogen Evolution.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
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The trial behind it
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Who cites it
19 citing papers in PubMed, 97 citations in OpenAlex.
- From Metal-Centered Catalysis to Organic Orbital Programming in Photoelectrocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Imine Linkage Isomerism in Layer-Entangled Three-Dimensional Covalent Organic Frameworks Modulates Fluorescent Sensing.Angewandte Chemie (International ed. in English) · 2026Article
- Ambient one-step synthesis and direct coating of highly crystalline covalent organic frameworks on arbitrary surfaces.Science advances · 2026Article
- Covalent Organic Framework-Carbon Nanotube Core-Shell Nanohybrids for Enhanced Catalytic Site Utilization of Molecular Catalysts in COAngewandte Chemie (International ed. in English) · 2026Article
- Photogeneration of Hydrogen in Water via Self-Assembly-Induced Colloidal Covalent Organic Framework Particles.Small science · 2026Article
- Aqueous and Surfactant-Free Synthesis of Nanoscale Covalent Organic Frameworks.Angewandte Chemie (International ed. in English) · 2026Article
- Solvothermal Template-Induced Hierarchical Porosity in Covalent Organic Frameworks: A Pathway to Enhanced Diffusivity.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Identifying Bottlenecks in the Photocatalytic Oxygen Evolution Reaction with Covalent Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- Robust dioxin-linked metallophthalocyanine tbo topology covalent organic frameworks and their photocatalytic properties.National science review · 2025Article
- Diffusion limited synthesis of wafer-scale covalent organic framework films for adaptative visual device.Nature communications · 2024Article
- Photochemical and Patternable Synthesis of 2D Covalent Organic Framework Thin Film Using Dynamic Liquid/Solid Interface.Small methods · 2024Article
- Homo-Nuclear Hetero-Atomic Conjugated Reticular Oligomers for Heterojunction: A Novel "Electron Medium" for Panel Photoelectrocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Photons, Excitons, and Electrons in Covalent Organic Frameworks.Journal of the American Chemical Society · 2024Review
- Chromatic covalent organic frameworks enabling in-vivo chemical tomography.Nature communications · 2024Article
- Molecular and Heterojunction Device Engineering of Solution-Processed Conjugated Reticular Oligomers: Enhanced Photoelectrochemical Hydrogen Evolution through High-Effective Exciton Separation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Covalent Organic Frameworks as Single-Site Photocatalysts for Solar-to-Fuel Conversion.Journal of the American Chemical Society · 2024Review
- Recent progress of covalent organic frameworks membranes: Design, synthesis, and application in water treatment.Eco-Environment & Health · 2023Review
- Computation-based regulation of excitonic effects in donor-acceptor covalent organic frameworks for enhanced photocatalysis.Nature communications · 2023Article
- A Heterostructure Photoelectrode Based on Two-Dimensional Covalent Organic Framework Film Decorated TiOMolecules (Basel, Switzerland) · 2023Article
Corrections and comments
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Authors and funding
16 authors at 5 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
As covalent organic frameworks (COFs) are coming of age, the lack of effective approaches to achieve crystalline and centimeter-scale-homogeneous COF films remains a significant bottleneck toward advancing the application of COFs in optoelectronic devices. Here, we present the synthesis of colloidal COF nanoplates, with lateral sizes of ∼200 nm and average heights of 35 nm, and their utilization as photocathodes for solar hydrogen evolution. The resulting COF nanoplate colloid exhibits a unimodal particle-size distribution and an exceptional colloidal stability without showing agglomeration after storage for 10 months and enables smooth, homogeneous, and thickness-tunable COF nanofilms via spin coating. Photoelectrodes comprising COF nanofilms were fabricated for photoelectrochemical (PEC) solar-to-hydrogen conversion. By rationally designing multicomponent photoelectrode architectures including a polymer donor/COF heterojunction and a hole-transport layer, charge recombination in COFs is mitigated, resulting in a significantly increased photocurrent density and an extremely positive onset potential for PEC hydrogen evolution (over +1 V against the reversible hydrogen electrode), among the best of classical semiconductor-based photocathodes. This work thus paves the way toward fabricating solution-processed large-scale COF nanofilms and heterojunction architectures and their use in solar-energy-conversion devices.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.