Evidence map›Paper›PMID 35655574›Full record

ArticleChemical science2022

The Janus face of high trans-effect carbenes in olefin metathesis: gateway to both productivity and decomposition.

Giovanni Occhipinti, Daniel L Nascimento, Marco Foscato, Deryn E Fogg, Vidar R Jensen

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Article
  3. B(COrganometallics · 2024
    Article
  4. Article
  5. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Giovanni OcchipintiDepartment of Chemistry, University of Bergen Allégaten 41 N-5007 Bergen Norway Giovanni.Occhipinti@uib.no Deryn.Fogg@uib.no Vidar.Jensen@uib.no.ORCID https://orcid.org/0000-0002-7279-6322
Daniel L NascimentoCenter for Catalysis Research & Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa Ottawa Canada K1N 6N5 dfogg@uottawa.ca.
Marco FoscatoDepartment of Chemistry, University of Bergen Allégaten 41 N-5007 Bergen Norway Giovanni.Occhipinti@uib.no Deryn.Fogg@uib.no Vidar.Jensen@uib.no.ORCID https://orcid.org/0000-0001-7762-6931
Deryn E FoggDepartment of Chemistry, University of Bergen Allégaten 41 N-5007 Bergen Norway Giovanni.Occhipinti@uib.no Deryn.Fogg@uib.no Vidar.Jensen@uib.no.ORCID https://orcid.org/0000-0002-4528-1139
Vidar R JensenDepartment of Chemistry, University of Bergen Allégaten 41 N-5007 Bergen Norway Giovanni.Occhipinti@uib.no Deryn.Fogg@uib.no Vidar.Jensen@uib.no.ORCID https://orcid.org/0000-0003-2444-3220

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Ruthenium-cyclic(alkyl)(amino)carbene (CAAC) catalysts, used at ppm levels, can enable dramatically higher productivities in olefin metathesis than their N-heterocyclic carbene (NHC) predecessors. A key reason is the reduced susceptibility of the metallacyclobutane (MCB) intermediate to decomposition

Identifiers

PMID35655574
PMCPMC9093171

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.