Evidence map›Paper›PMID 35655006›Full record

ArticleNature chemistry2022

Low-valent tungsten redox catalysis enables controlled isomerization and carbonylative functionalization of alkenes.

Tanner C Jankins, William C Bell, Yu Zhang, Zi-Yang Qin, Jason S Chen, Milan Gembicky, Peng Liu, Keary M Engle

Abstract read
In one paragraph

Article in Nature chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Tungsten's tandem transformation.Nature chemistry · 2022
    Article
  10. Article
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

8 authors.

Tanner C JankinsDepartment of Chemistry, The Scripps Research Institute, La Jolla, CA, USA.ORCID http://orcid.org/0000-0002-4408-9751
William C BellDepartment of Chemistry, University of Pittsburgh, Pittsburgh, PA, USA.
Yu ZhangDepartment of Chemistry, University of Pittsburgh, Pittsburgh, PA, USA.
Zi-Yang QinDepartment of Chemistry, The Scripps Research Institute, La Jolla, CA, USA.ORCID http://orcid.org/0000-0001-7356-6927
Jason S ChenAutomated Synthesis Facility, The Scripps Research Institute, La Jolla, CA, USA.
Milan GembickyDepartment of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA, USA.ORCID http://orcid.org/0000-0002-3898-1612
Peng LiuDepartment of Chemistry, University of Pittsburgh, Pittsburgh, PA, USA. pengliu@pitt.edu.ORCID http://orcid.org/0000-0002-8188-632X
Keary M EngleDepartment of Chemistry, The Scripps Research Institute, La Jolla, CA, USA. keary@scripps.edu.ORCID http://orcid.org/0000-0003-2767-6556

Funding

Combinatorial, Catalytic Functionalization of Alkenes and AlkynesR35GM125052 · NIGMS · SCRIPPS RESEARCH INSTITUTE, THE · PI ENGLE, KEARY MARK · 2017 to 2021
$2.9M
Computational Models for Reactivity and Selectivity in Transition Metal-Catalyzed Olefin FunctionalizationR35GM128779 · NIGMS · UNIVERSITY OF PITTSBURGH AT PITTSBURGH · PI Peng Liu · 2018 to 2026
$2.9M
Parallel Pressure Reactor with Sampling CapabilitiesS10OD025208 · OD · SCRIPPS RESEARCH INSTITUTE, THE · PI CHEN, JASON SHIH-HAO · 2018 to 2018
$591k
NIGMS NIH HHS R35 GM125052NIGMS NIH HHS R35 GM128779NIH HHS S10 OD025208
6 · The paper itself

Abstract

The controlled isomerization and functionalization of alkenes is a cornerstone achievement in organometallic catalysis that is now widely used throughout industry. In particular, the addition of CO and H

Indexed as

AlkenesTungstenCatalysisIsomerismOxidation-ReductionAlkenesTungsten

Identifiers

PMID35655006
PMCPMC9674112

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.