ArticleAngewandte Chemie (International ed. in English)2022
Intramolecular Energy and Solvent-Dependent Chirality Transfer within a BINOL-Perylene Hetero-Cyclophane.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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14 citing papers in PubMed, 72 citations in OpenAlex.
- Regioisomer-Dependent Supramolecular Assembly of Coumarin Derivatives for Wavelength-Dependent Blue and Near-Infrared Circularly Polarized Luminescence.Angewandte Chemie (International ed. in English) · 2026Article
- Design and synthesis of a tetraphenylethene-porphyrin hetero-faced molecular cage for photodynamic therapy.National science review · 2026Article
- Delicate molecular design, self-assembly and functional applications of chiral cyclophanes.Chemical science · 2026Review
- Precise Construction of Helical Unimolecular Micelles from Poly(phenylacetylene)s for Tunable Circularly Polarized Luminescence and Sensing.Precision chemistry · 2026Article
- Merging dynamic and static chirality in propeller-shaped carbazole oligomersRSC advances · 2026Article
- Circular Dichroism and Multiphoton Circularly Polarized Luminescence Switching Using a Bis-perylene Diimide Macrocycle.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- A Bis-Perylene Diimide Macrocycle Chiroptical Switch.Angewandte Chemie (International ed. in English) · 2025Article
- Control of Dynamic Chirality in Donor-Acceptor Fluorophores.Angewandte Chemie (International ed. in English) · 2025Article
- Boosting the circularly polarized luminescence of pyrene-tiaraed pillararenes through mechanically locking.Nature communications · 2024Article
- Investigating the diastereoselective synthesis of a macrocycle under Curtin-Hammett control.Chemical science · 2024Article
- "Gear-driven"-type chirality transfer of tetraphenylethene-based supramolecular organic frameworks for peptides in water.Chemical science · 2024Article
- BINOL-like atropisomeric chiral nanographene.Chemical science · 2023Article
- Preferential molecular recognition of heterochiral guests within a cyclophane receptor.Nature communications · 2023Article
- Intramolecular Energy and Solvent-Dependent Chirality Transfer within a BINOL-Perylene Hetero-Cyclophane.Angewandte Chemie (International ed. in English) · 2022Article
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6 authors at 2 institutions in 1 country.
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Abstract
Multichromophoric macrocycles and cyclophanes are important supramolecular architectures for the elucidation of interchromophoric interactions originating from precise spatial organization. Herein, by combining an axially chiral binaphthol bisimide (BBI) and a bay-substituted conformationally labile twisted perylene bisimide (PBI) within a cyclophane of well-defined geometry, we report a chiral PBI hetero-cyclophane (BBI-PBI) that shows intramolecular energy and solvent-regulated chirality transfer from the BBI to the PBI subunit. Excellent spectral overlap and spatial arrangement of BBI and PBI lead to efficient excitation energy transfer and subsequent PBI emission with high quantum yield (80-98 %) in various solvents. In contrast, chirality transfer is strongly dependent on the respective solvent as revealed by circular dichroism (CD) spectroscopy. The combination of energy and chirality transfer affords a bright red circularly polarized luminescence (CPL) from the PBI chromophore by excitation of BBI.
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