ArticleJournal of the American Chemical Society2022
Direct Detection of Lithium Exchange across the Solid Electrolyte Interphase by
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed, 34 citations in OpenAlex.
- Probing the Phase and Mechanism of Captured COChemistry of materials : a publication of the American Chemical Society · 2026Article
- Solid-State NMR Investigation of Electrolyte Effects on Silicon-Graphite Composite Anode: Solid Electrolyte Interphase Formation and Failure Mechanisms.Chemistry of materials : a publication of the American Chemical Society · 2026Article
- Direct and in situ examination of LiProceedings of the National Academy of Sciences of the United States of America · 2025Article
- Elucidating Surface Adsorption of Lithium Ions on Electrode Materials UsingJournal of the American Chemical Society · 2025Article
- Sensitive Detection of Dendritic Lithium Morphologies by Dynamic Nuclear Polarization.The journal of physical chemistry letters · 2025Article
- Grain-Boundary-Rich Interphases for Rechargeable Batteries.Journal of the American Chemical Society · 2024Article
- Tracking dendrites and solid electrolyte interphase formation with dynamic nuclear polarization-NMR spectroscopy.Nature communications · 2024Article
- The lasting impact of formation cycling on the Li-ion kinetics between SEI and the Li-metal anode and its correlation with efficiency.Science advances · 2024Article
- Biphasic NMR of Hyperpolarized Suspensions-Real-Time Monitoring of Solute-to-Solid Conversion to Watch Materials Grow.The journal of physical chemistry. C, Nanomaterials and interfaces · 2023Article
Corrections and comments
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Authors and funding
8 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Lithium metal anodes offer a huge leap in the energy density of batteries, yet their implementation is limited by solid electrolyte interphase (SEI) formation and dendrite deposition. A key challenge in developing electrolytes leading to the SEI with beneficial properties is the lack of experimental approaches for directly probing the ionic permeability of the SEI. Here, we introduce lithium chemical exchange saturation transfer (Li-CEST) as an efficient nuclear magnetic resonance (NMR) approach for detecting the otherwise invisible process of Li exchange across the metal-SEI interface. In Li-CEST, the properties of the undetectable SEI are encoded in the NMR signal of the metal resonance through their exchange process. We benefit from the high surface area of lithium dendrites and are able, for the first time, to detect exchange across solid phases through CEST. Analytical Bloch-McConnell models allow us to compare the SEI permeability formed in different electrolytes, making the presented Li-CEST approach a powerful tool for designing electrolytes for metal-based batteries.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.