Evidence map›Paper›PMID 35631822›Full record

ArticlePolymers2022

Process-Induced Morphology of Poly(Butylene Adipate Terephthalate)/Poly(Lactic Acid) Blown Extrusion Films Modified with Chain-Extending Cross-Linkers.

Juliana V C Azevedo, Esther Ramakers-van Dorp, Roman Grimmig, Berenika Hausnerova, Bernhard Möginger

Abstract read
In one paragraph

Article in Polymers, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Juliana V C AzevedoFaculty of Technology, Tomas Bata University in Zlín, Vavreckova 275, 760 01 Zlín, Czech Republic.ORCID 0000-0002-1534-1436
Esther Ramakers-van DorpDepartment of Natural Sciences, University of Applied Sciences Bonn-Rhein-Sieg, von Liebig Str. 20, 53359 Rheinbach, Germany.
Roman GrimmigDepartment of Natural Sciences, University of Applied Sciences Bonn-Rhein-Sieg, von Liebig Str. 20, 53359 Rheinbach, Germany.ORCID 0000-0003-1708-6018
Berenika HausnerovaFaculty of Technology, Tomas Bata University in Zlín, Vavreckova 275, 760 01 Zlín, Czech Republic.ORCID 0000-0002-6368-7896
Bernhard MögingerDepartment of Natural Sciences, University of Applied Sciences Bonn-Rhein-Sieg, von Liebig Str. 20, 53359 Rheinbach, Germany.

Funding

Ministry of Education Youth and Sports DKRVO (RP/CPS/2022/003)
6 · The paper itself

Abstract

Process-induced changes in the morphology of biodegradable polybutylene adipate terephthalate (PBAT) and polylactic acid (PLA) blends modified with various multifunctional chain-extending cross-linkers (CECLs) are presented. The morphology of unmodified and modified films produced with blown film extrusion is examined in an extrusion direction (ED) and a transverse direction (TD). While FTIR analysis showed only small peak shifts indicating that the CECLs modify the molecular weight of the PBAT/PLA blend, SEM investigations of the fracture surfaces of blown extrusion films revealed their significant effect on the morphology formed during the processing. Due to the combined shear and elongation deformation during blown film extrusion, rather spherical PLA islands were partly transformed into long fibrils, which tended to decay to chains of elliptical islands if cooled slowly. The CECL introduction into the blend changed the thickness of the PLA fibrils, modified the interface adhesion, and altered the deformation behavior of the PBAT matrix from brittle to ductile. The results proved that CECLs react selectively with PBAT, PLA, and their interface. Furthermore, the reactions of CECLs with PBAT/PLA induced by the processing depended on the deformation directions (ED and TD), thus resulting in further non-uniformities of blown extrusion films.

Indexed as

blown film extrusionchain-extending cross-linkerpoly(butylene adipate terephthalate)poly(lactic acid)process-induced morphology

Identifiers

PMID35631822
PMCPMC9144630

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.