ArticleNanomaterials (Basel, Switzerland)2022
Electron-Induced Decomposition of Different Silver(I) Complexes: Implications for the Design of Precursors for Focused Electron Beam Induced Deposition.
Article in Nanomaterials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Ligand Co-Deposition in Focused Electron Beam Induced Nanoprinting: A Predictive Composition Model.Small methods · 2026Article
- Focused electron beam-induced deposition from Ru(CO)₄(fumaronitrile): incomplete carbonyl loss and nitrogen retention.The European physical journal. D, Atomic, molecular, and optical physics · 2026Article
- Evaluating metal-organic precursors for focused ion beam-induced deposition through solid-layer decomposition analysis.Beilstein journal of nanotechnology · 2025Article
- Silver CVD and ALD Precursors: Synthesis, Properties, and Application in Deposition Processes.Molecules (Basel, Switzerland) · 2024Review
- Direct electron beam writing of silver using a β-diketonate precursor: first insights.Beilstein journal of nanotechnology · 2024Article
- Ligand Size and Carbon-Chain Length Study of Silver Carboxylates in Focused Electron-Beam-Induced Deposition.Nanomaterials (Basel, Switzerland) · 2023Article
- In Situ Time-of-Flight Mass Spectrometry of Ionic Fragments Induced by Focused Electron Beam Irradiation: Investigation of Electron Driven Surface Chemistry inside an SEM under High Vacuum.Nanomaterials (Basel, Switzerland) · 2022Article
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Focused electron beam induced deposition (FEBID) is a versatile tool to produce nanostructures through electron-induced decomposition of metal-containing precursor molecules. However, the metal content of the resulting materials is often low. Using different Ag(I) complexes, this study shows that the precursor performance depends critically on the molecular structure. This includes Ag(I) 2,2-dimethylbutanoate, which yields high Ag contents in FEBID, as well as similar aliphatic Ag(I) carboxylates, aromatic Ag(I) benzoate, and the acetylide Ag(I) 3,3-dimethylbutynyl. The compounds were sublimated on inert surfaces and their electron-induced decomposition was monitored by electron-stimulated desorption (ESD) experiments in ultrahigh vacuum and by reflection-absorption infrared spectroscopy (RAIRS). The results reveal that Ag(I) carboxylates with aliphatic side chains are particularly favourable for FEBID. Following electron impact ionization, they fragment by loss of volatile CO
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