ArticleNanomaterials (Basel, Switzerland)2022
Nitrogen- and Halogen-Free Multifunctional Polymer-Directed Fabrication of Aluminum-Rich Hierarchical MFI Zeolites.
Article in Nanomaterials (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Disinfectant-Assisted Preparation of Hierarchical ZSM-5 Zeolite with Excellent Catalytic Stabilities in Propane Aromatization.Nanomaterials (Basel, Switzerland) · 2024Article
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5 authors.
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Abstract
Aluminum-rich hierarchical MFI-type zeolites with high acidic-site density exhibit excellent activity and selectivity in bulky molecule-involved reactions. However, it is challenging to develop a facile and environmentally benign method for fabricating them. Herein, we employ a polymer that does not contain nitrogen and halogen elements to successfully synthesize aluminum-rich hierarchical ZSM-5 zeolite with a Si/Al ratio of 8 and a significant number of mesopores comprised of oriented-assembled nanocrystals. It is demonstrated that the nitrogen- and halogen-free polymer is instrumental in the formation of the ZSM-5 zeolite by serving as a template for constructing the hierarchical micro/mesoporous structure. Moreover, this polymer also acts as a crystal growth modifier to form a single-crystalline zeolite. Notably, the resultant zeolite shows a better catalytic performance in converting waste plastic into hydrocarbons than a commercial one. Our work enables the synthesis of high-quality hierarchical zeolites without requiring quaternary ammonium templates.
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