ArticleJournal of the American Chemical Society2022
Controlling One- or Two-Electron Oxidation for Selective Amine Functionalization by Alternating Current Frequency.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
20 citing papers in PubMed, 71 citations in OpenAlex.
- Selective Electrosynthesis of High-Concentration MnAngewandte Chemie (International ed. in English) · 2026Article
- Beyond traditional defunctionalized cross-coupling reaction: scope, limitations, practicability & future prospects of recent electrochemical methodologies.RSC advances · 2026Review
- Alternating Current-Driven Hydrogen Isotope Labeling of Aliphatic Amines Using 1,3-Propanedithiol as an Efficient Hydrogen Atom Transfer Reagent.Journal of the American Chemical Society · 2026Article
- Alternating-Polarity Electrolysis Enables Efficient Enantioselective Semipinacol Rearrangement Using Sodium Chloride.Journal of the American Chemical Society · 2026Article
- Floquet States of Chemoselective Alternating Current Electrosynthesis.Journal of the American Chemical Society · 2026Article
- Applying asymmetric-waveform alternating current in nickel-catalyzed asymmetric reductive cross-coupling.Nature communications · 2026Article
- Energy Upconversion Using Platinum(II)-BPI Photosensitizers.Inorganic chemistry · 2025Article
- Nickelaelectro-Catalyzed C─H Activation to β-Arylated Pyrroles via Multiple Dehydrogenation.Angewandte Chemie (International ed. in English) · 2025Article
- A Diverse Array of Catalytic Photoredox Reactions Based on Aluminum(III)-Salen Complexes: Understanding the Enhancement of Catalytic Activity via Amine Association.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Origin of Selectivity in Alternating Current-Enabled Partial Reduction of (Hetero)Arenes: A Case Study of Two Consecutive Irreversible Electrochemical Steps.Journal of the American Chemical Society · 2025Article
- Microdroplet-Mediated Multiphase Cycling in a Cloud of Water Drives Chemoselective Electrolysis.Journal of the American Chemical Society · 2024Article
- Optimizing Cu electrocatalysis using programmed alternating current.National science review · 2024Article
- Electrochemical Glycosylation via Halogen-Atom-Transfer forACS catalysis · 2024Article
- Intricacies of Mass Transport during Electrocatalysis: A Journey through Iron Porphyrin-Catalyzed Oxygen Reduction.Journal of the American Chemical Society · 2024Article
- Revisiting Alternating Current Electrolysis for Organic Synthesis.Current opinion in electrochemistry · 2024Article
- Pulsed electrolysis: enhancing primary benzylic C(spOrganic chemistry frontiers : an international journal of organic chemistry · 2024Article
- Electrochemical hydrogen isotope exchange of amines controlled by alternating current frequency.Faraday discussions · 2023Article
- Overcoming the Potential Window-Limited Functional Group Compatibility by Alternating Current Electrolysis.Journal of the American Chemical Society · 2023Article
- Wireless Electrochemical Reactor for Accelerated Exploratory Study of Electroorganic Synthesis.ACS central science · 2023Article
- Study of the Electrochemical Behavior of N-Substituted-4-Piperidones Curcumin Analogs: A Combined Experimental and Theoretical Approach.International journal of molecular sciences · 2022Article
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 2 countries.
Funding
Abstract
Here, we report a unique electrosynthetic method that enables the selective one-electron oxidation of tertiary amines to generate α-amino radical intermediates over two-electron oxidation to iminium cations, providing easy access to arylation products by simply applying an optimal alternating current (AC) frequency. More importantly, we have discovered an electrochemical descriptor from cyclic voltammetry studies to predict the optimal AC frequency for various amine substrates, circumventing the time-consuming trial-and-error methods for optimizing reaction conditions. This new development in AC electrolysis provides an alternative strategy to solving challenging chemoselectivity problems in synthetic organic chemistry.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.