Evidence map›Paper›PMID 35618767›Full record

ArticleNature chemistry2022

Chiral control of spin-crossover dynamics in Fe(II) complexes.

Malte Oppermann, Francesco Zinna, Jérôme Lacour, Majed Chergui

Abstract read
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In one paragraph

Article in Nature chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.

0numbers the graph read from it
0cells of the map it votes in
28citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

28 citing papers in PubMed.

  1. Article
  2. Uncovering Correlations between Structure and Valence Tautomerism in Cobalt-o-Dioxolene Crystals.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026
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  18. Dalton transactions (Cambridge, England : 2003) · 2024
    Article
  19. Multifaceted Deactivation Dynamics of Fe(II)The journal of physical chemistry. A · 2023
    Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Malte OppermannLaboratory of Ultrafast Spectroscopy (LSU) and Lausanne Centre for Ultrafast Science (LACUS), École Polytechnique Fédérale de Lausanne, ISIC-FSB, Lausanne, Switzerland. malte.oppermann@epfl.ch.ORCID http://orcid.org/0000-0002-3257-686X
Francesco ZinnaDipartimento di Chimica e Chimica Industriale, Università di Pisa, Pisa, Italy.ORCID http://orcid.org/0000-0002-6331-6219
Jérôme LacourDépartement de Chimie Organique, Université de Genève, Geneva, Switzerland.ORCID http://orcid.org/0000-0001-6247-8059
Majed CherguiLaboratory of Ultrafast Spectroscopy (LSU) and Lausanne Centre for Ultrafast Science (LACUS), École Polytechnique Fédérale de Lausanne, ISIC-FSB, Lausanne, Switzerland.ORCID http://orcid.org/0000-0002-4856-226X

Funding

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation) NCCR MUST
6 · The paper itself

Abstract

Iron-based spin-crossover complexes hold tremendous promise as multifunctional switches in molecular devices. However, real-world technological applications require the excited high-spin state to be kinetically stable-a feature that has been achieved only at cryogenic temperatures. Here we demonstrate high-spin-state trapping by controlling the chiral configuration of the prototypical iron(II)tris(4,4'-dimethyl-2,2'-bipyridine) in solution, associated for stereocontrol with the enantiopure Δ- or Λ-enantiomer of tris(3,4,5,6-tetrachlorobenzene-1,2-diolato-κ

Identifiers

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.