ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Triplet-triplet Annihilation Dynamics of Naphthalene.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
11 citing papers in PubMed.
- Collective Rabi-Driven Vibrational Activation in Molecular Polaritons.Nano letters · 2026Article
- Breaking the 1250 nm Barrier: A Computational Approach to Light Upconversion via Triplet-Triplet Annihilation in the Silica Telecom Band.ACS applied energy materials · 2026Article
- Enhancing the statistical probability factor in triplet-triplet annihilation photon upconversionChemical science · 2025Article
- Localized and Excimer Triplet Electronic States of Naphthalene Dimers: A Computational Study.Molecules (Basel, Switzerland) · 2025Article
- Unraveling a Cavity-Induced Molecular Polarization Mechanism from Collective Vibrational Strong Coupling.The journal of physical chemistry letters · 2024Article
- Derivatives of Phenyl Pyrimidine and of the Different Donor Moieties as Emitters for OLEDs.Materials (Basel, Switzerland) · 2024Article
- Cavity-Modified Chemiluminescent Reaction of Dioxetane.The journal of physical chemistry. A · 2023Article
- Bulky Substituents Promote Triplet-Triplet Annihilation Over Triplet Excimer Formation in Naphthalene Derivatives.Journal of the American Chemical Society · 2023Article
- Cavity Born-Oppenheimer Hartree-Fock Ansatz: Light-Matter Properties of Strongly Coupled Molecular Ensembles.The journal of physical chemistry letters · 2023Article
- The role of dephasing for dark state coupling in a molecular Tavis-Cummings model.The Journal of chemical physics · 2023Article
- Triplet-triplet Annihilation Dynamics of Naphthalene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
Abstract
Triplet-triplet annihilation (TTA) is a spin-allowed conversion of two triplet states into one singlet excited state, which provides an efficient route to generate a photon of higher frequency than the incident light. Multiple energy transfer steps between absorbing (sensitizer) and emitting (annihilator) molecular species are involved in the TTA based photon upconversion process. TTA compounds have recently been studied for solar energy applications, even though the maximum upconversion efficiency of 50 % is yet to be achieved. With the aid of quantum calculations and based on a few key requirements, several design principles have been established to develop the well-functioning annihilators. However, a complete molecular level understanding of triplet fusion dynamics is still missing. In this work, we have employed multi-reference electronic structure methods along with quantum dynamics to obtain a detailed and fundamental understanding of TTA mechanism in naphthalene. Our results suggest that the TTA process in naphthalene is mediated by conical intersections. In addition, we have explored the triplet fusion dynamics under the influence of strong light-matter coupling and found an increase of the TTA based upconversion efficiency.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.