ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Photo-Induced Halogen-Atom Transfer: Generation of Halide Radicals for Selective Hydrohalogenation Reactions.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Cobalt-Catalyzed Alkene Hydrohalogenation via Hydrogen Atom Transfer.Tetrahedron · 2025Article
- Article
- Red Light and Supersilane: A Novel Pathway for Hydrofunctionalizations and Giese Reactions.ACS organic & inorganic Au · 2025Article
- Sustainable Photoinduced Decarboxylative Chlorination Mediated by Halogen Atom Transfer.Green chemistry : an international journal and green chemistry resource : GC · 2023Article
- Photo-Induced Halogen-Atom Transfer: Generation of Halide Radicals for Selective Hydrohalogenation Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
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Authors and funding
4 authors.
Funding
Abstract
The first photo-mediated process enabling the generation of halide radicals by Halogen-Atom Transfer (XAT) is described. Contrary to radical transformations involving XAT reactivity, which exploit stable carbon radicals, this unique approach uses 1,2-dihaloethanes for the generation of unstable carbon radicals by XAT. These transient radicals then undergo β-scission with release of ethylene and formation of more stable halide radicals which have been used in selective hydrohalogenations of a large number of unsaturated hydrocarbons, including Michael acceptors, unactivated alkenes and alkynes. This hydrohalogenation is tolerant of a broad range of functionalities and is believed to proceed through a radical-chain manifold that propagates by the use of silane derivatives.
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