ArticleThe journal of physical chemistry. B2022
Deep Eutectic Solvents or Eutectic Mixtures? Characterization of Tetrabutylammonium Bromide and Nonanoic Acid Mixtures.
Article in The journal of physical chemistry. B, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
9 citing papers in PubMed, 78 citations in OpenAlex.
- In situ formation of hydrophobic deep eutectic solvents for ultrasound-assisted microextraction: a greener pathway for monitoring the migration and residue of polychlorinated biphenyls in food contact paper.Analytical and bioanalytical chemistry · 2026Article
- Shelf life and time-resolved thermal, chemical, and thermodynamic characterization of four hydrophobic deep eutectic solvents.RSC advances · 2026Article
- Hydrophobic Deep Eutectic Solvent-Enhanced Filaments: A Green Breakthrough for Additive-Manufactured Electrodes.ChemSusChem · 2026Article
- Synthesis and application of a deep eutectic solvent as a green catalyst for use in oil esterification: DOE optimization and method greenness analysis.RSC advances · 2025Article
- Deep Eutectic Inks for Multiphoton 3D Laser Microprinting.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Fluorimetric Determination of Eosin Y in Water Samples and Drinks Using Deep Eutectic Solvent-Based Liquid-Phase Microextraction.Molecules (Basel, Switzerland) · 2025Article
- Exploring the effect of natural deep eutectic solvents on zein: Structural and functional properties.Current research in food science · 2025Article
- Conformational Geometry Matters: The Case of the Low-Melting-Point Systems of Tetrabutylammonium Triflate with Fumaric or Maleic Acid.Molecules (Basel, Switzerland) · 2024Article
- Estimating the phase diagrams of deep eutectic solvents within an extensive chemical space.Communications chemistry · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 3 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Deep eutectic solvents have quickly attracted the attention of researchers because they better meet the requirements of green chemistry and thus have the potential to replace conventional hazardous organic solvents in some areas. To better understand the nature of these mixtures, as well as expand the possibilities of their use in different industries, a detailed examination of their physical properties, such as density, viscosity, the nature of the interactions between their constituents, the phase diagrams, depression of their melting point, and interpretation of these results is necessary. In this work, the mixtures of tetrabutylammonium bromide (TBAB) and nonanoic acid (NA) in different molar ratios are theoretically and experimentally investigated by applying a phase diagram constructed on the basis of differential scanning calorimetry measurements and COSMO-RS model. Spectral properties are investigated based on Fourier transform infrared spectroscopy and density functional theory. The observed eutectic point indicates the formation of a DES in the TBAB-NA system in a 1:2 molar ratio. This is due to the presence of hydrogen bonds between the carboxyl group from the NA molecule and the bromine atom from the TBAB molecule. Other eutectic mixtures are most likely the solutions of TBAB in NA, in which hydrogen bonds predominate between acid molecules.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.