ArticleNature communications2022
Controllable multiple-step configuration transformations in a thermal/photoinduced reaction.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Beyond geometric constraint: dynamic fluid-lattice-activated topochemical polymerization.National science review · 2026Article
- Synergistic Ni-Co Metal Nodes in a Conjugated MOF-Modified Separator for High-Performance Lithium-Sulfur Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- In-situ photomechanical bending in a photosalient Zn-based coordination polymer probed by photocrystallography.Communications chemistry · 2025Article
- [2 + 2] cycloaddition and its photomechanical effects on 1D coordination polymers with reversible amide bonds and coordination site regulation.Chemical science · 2024Article
- Synergism of Light-Induced [4 + 4] Cycloaddition and Electron Transfer Toward Switchable Photoluminescence and Single-Molecule Magnet Behavior in a DyResearch (Washington, D.C.) · 2024Article
- In situ observation of a stepwise [2 + 2] photocycloaddition process using fluorescence spectroscopy.Nature communications · 2023Article
- Regulating photosalient behavior in dynamic metal-organic crystals.Communications chemistry · 2023Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Solid-state photochemical reactions of olefinic compounds have been demonstrated to represent powerful access to organic cyclic molecules with specific configurations. However, the precise control of the stereochemistry in these reactions remains challenging owing to complex and fleeting configuration transformations. Herein, we report a unique approach to control the regiospecific configurations of C = C groups and the intermediates by varying temperatures in multiple-step thermal/photoinduced reactions, thus successfully realizing reversible ring closing/opening changes using a single-crystal coordination polymer platform. All stereochemical transitions are observed by in situ single-crystal X-ray diffraction, powder X-ray diffraction and infrared spectroscopy. Density functional theory calculations allow us to rationalize the mechanism of the synergistic thermal/photoinduced transformations. This approach can be generalized to the analysis of the possible configuration transformations of functional groups and intermediates and unravel the detailed mechanism for any inorganic, organic and macromolecular reactions susceptible to incorporation into single-crystal coordination polymer platforms.
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Registered trials
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