Evidence map›Paper›PMID 35605020›Full record

ArticleEnvironmental science & technology2022

Oil Irradiation Experiments Document Changes in Oil Properties, Molecular Composition, and Dispersant Effectiveness Associated with Oil Photo-Oxidation.

Christoph Aeppli, Douglas A Mitchell, Phoebe Keyes, Erin C Beirne, Kelly M McFarlin, Alina T Roman-Hubers, Ivan Rusyn, Roger C Prince, Lin Zhao, Thomas F Parkerton and 1 more

Open access · greenAbstract read
In one paragraph

Article in Environmental science & technology, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
1.5field-weighted citation impact, top 20% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 29 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors at 4 institutions in 1 country.

Christoph AeppliBigelow Laboratory for Ocean Sciences, East Boothbay, Maine 04544, United States.ORCID 0000-0002-3758-0163
Douglas A MitchellIndependent Consultant, Tomball, Texas 77375, United States.
Phoebe KeyesBigelow Laboratory for Ocean Sciences, East Boothbay, Maine 04544, United States.
Erin C BeirneBigelow Laboratory for Ocean Sciences, East Boothbay, Maine 04544, United States.
Kelly M McFarlinExxonMobil Biomedical Sciences Inc., Clinton, New Jersey 08809, United States.
Alina T Roman-HubersDepartment of Veterinary Integrative Biosciences, Texas A&M University, College Station, Texas 77843, United States.
Ivan RusynDepartment of Veterinary Integrative Biosciences, Texas A&M University, College Station, Texas 77843, United States.
Roger C PrinceStonybrook Apiary, Pittstown, New Jersey 08867, United States.ORCID 0000-0002-5174-4216
Lin ZhaoExxonMobil Upstream Research Company, Spring, Texas 77389, United States.
Thomas F ParkertonEnviSci Consulting, LLC, Austin, Texas 77433, United States.
Tim NedwedExxonMobil Upstream Research Company, Spring, Texas 77389, United States.ORCID 0000-0001-6555-8281
Bigelow Laboratory for Ocean Sciences · USExxonMobil (United States) · USTexas A&M University · USLone Star College–Tomball · US

Funding

Single cell, multi-parametric high throughput platform to classify endocrine disruptor potential of mixturesP42ES027704 · NIEHS · TEXAS A&M UNIVERSITY · PI Weihsueh A Chiu · 2017 to 2026
$21.2M
Regulatory Science in Environmental Health and ToxicologyT32ES026568 · NIEHS · TEXAS A&M UNIVERSITY · PI Weihsueh A Chiu, Natalie M Johnson · 2016 to 2026
$3.8M
NIEHS NIH HHS P42 ES027704NIEHS NIH HHS T32 ES026568
6 · The paper itself

Abstract

While chemical dispersants are a powerful tool for treating spilled oil, their effectiveness can be limited by oil weathering processes such as evaporation and emulsification. It has been suggested that oil photo-oxidation could exacerbate these challenges. To address the role of oil photo-oxidation in dispersant effectiveness, outdoor mesocosm experiments with crude oil on seawater were performed. Changes in bulk oil properties and molecular composition were quantified to characterize oil photo-oxidation over 11 days. To test relative dispersant effectiveness, oil residues were evaluated using the Baffled Flask Test. The results show that oil irradiation led to oxygen incorporation, formation of oxygenated hydrocarbons, and higher oil viscosities. Oil irradiation was associated with decreased dispersant efficacy, with effectiveness falling from 80 to <50% in the Baffled Flask Test after more than 3 days of irradiation. Increasing photo-oxidation-induced viscosity seems to drive the decreasing dispersant effectiveness. Comparing the Baffled Flask Test results with field data from the Deepwater Horizon oil spill showed that laboratory dispersant tests underestimate the dispersion of photo-oxidized oil in the field. Overall, the results suggest that prompt dispersant application (within 2-4 days), as recommended by current oil spill response guidelines, is necessary for effective dispersion of spilled oil.

Indexed as

PetroleumPetroleum PollutionWater Pollutants, ChemicalHydrocarbonsSurface-Active AgentsHydrocarbonsPetroleumSurface-Active AgentsWater Pollutants, ChemicalBaffled Flask Testco-solventsion mobility spectrometry-mass spectrometryoil photodegradationphotoproductsviscosity

Identifiers

PMID35605020
PMCPMC9552565
OpenAlexW4281291935

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.