ArticleChemistry of materials : a publication of the American Chemical Society2021
Integration of Fluorescent Functionality into Pressure-Amplifying Metal-Organic Frameworks.
Article in Chemistry of materials : a publication of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 11 citations in OpenAlex.
- Probing the Limits of Mechanical Stability of the Mesoporous Metal-Organic Framework DUT-76(Cu) by Hydrocarbon Physisorption.ACS applied materials & interfaces · 2025Article
- Negative gas adsorption transitions and pressure amplification phenomena in porous frameworks.Chemical Society reviews · 2025Review
- Nanoporous Frameworks with High Porosity and Unexpected Rigid Framework Topologies Based on Odd-Numbered Ring-Expanded Linkers.Small science · 2023Article
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The flexibility of soft porous crystals, i.e., their ability to respond to external stimuli with structural changes, is one of the most fascinating features of metal-organic frameworks (MOFs). In addition to breathing and swelling phenomena of flexible MOFs, negative gas adsorption (NGA) and pressure amplification (PA) are the more recent discoveries in this field initially observed in the cubic DUT-49 framework. In recent years, the structural contraction was monitored by physisorption, X-ray diffraction, nuclear magnetic resonance (NMR), and electron paramagnetic resonance (EPR) techniques, providing only limited information about the electronic structure of the ligand. In this work, we designed a new ligand with a fluorescent core in the linker backbone and synthesized three new MOFs, isoreticular to DUT-49, denoted as DUT-140(M) (M-Cu, Co, Zn), crystallizing in the space group
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Registered trials
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