ArticleNature communications2022
Parts-per-million of ruthenium catalyze the selective chain-walking reaction of terminal alkenes.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed, 42 citations in OpenAlex.
- Palladium-Catalyzed Regiodivergent Telomerization of Isoprene With Oxindoles.Angewandte Chemie (International ed. in English) · 2026Article
- Contra-Thermodynamic Chain-Walking Isomerization: A Sustainable Tool for Selective Molecular Editing in Green Chemistry.ChemSusChem · 2026Article
- Chemical Upcycling of Nitrile Butadiene Rubbers to Polyamines and Polyols by Chemoselective Catalytic Hydrogenation.Angewandte Chemie (International ed. in English) · 2026Article
- Iron-catalyzed alkene isomerization and tandem functionalization.Communications chemistry · 2026Article
- PotassiumACS omega · 2026Article
- Carbonyl-Olefin/Alkyne Metathesis Reactions Catalyzed by Bifunctional H-USY Zeolites.Journal of the American Chemical Society · 2025Article
- Uncatalyzed aerobic epoxidation of liquid alkyl alkenes.Nature communications · 2025Article
- A Sequential Catalytic Carbonation-Hydrolysis-Diol Dehydrogenation Reaction of Epoxides.ChemPlusChem · 2025Article
- Random Access Memory (RAM) Contacts Waste Catalyzes Organic Reactions.Global challenges (Hoboken, NJ) · 2025Article
- Direct Synthesis of Polyesterether from Ethylene Glycol.ACS sustainable chemistry & engineering · 2025Article
- NJACS Au · 2024Article
- B(COrganometallics · 2024Article
- Alkene Isomerization Catalyzed by a Mn(I) Bisphosphine Borohydride Complex.ACS catalysis · 2024Article
- One-Pot Synthesis of Terminal Alkynes from Alkenes.JACS Au · 2024Article
- An air- and moisture-stable ruthenium precatalyst for diverse reactivity.Nature chemistry · 2024Article
- Evidence for Ruthenium(II) Peralkene Complexes as Catalytic Species during the Isomerization of Terminal Alkenes in Solution.Inorganic chemistry · 2023Article
- Noble metal catalyst detection in rocks using machine-learning: The future to low-cost, green energy materials?Scientific reports · 2023Article
Corrections and comments
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Authors and funding
7 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The chain-walking of terminal alkenes (also called migration or isomerization reaction) is currently carried out in industry with unselective and relatively costly processes, to give mixtures of alkenes with significant amounts of oligomerized, branched and reduced by-products. Here, it is shown that part-per-million amounts of a variety of commercially available and in-house made ruthenium compounds, supported or not, transform into an extremely active catalyst for the regioselective migration of terminal alkenes to internal positions, with yields and selectivity up to >99% and without any solvent, ligand, additive or protecting atmosphere required, but only heating at temperatures >150 °C. The resulting internal alkene can be prepared in kilogram quantities, ready to be used in nine different organic reactions without any further treatment.
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