ArticleJournal of the American Chemical Society2022
A Kinetic Isotope Effect in the Formation of Lanthanide Phosphate Nanocrystals.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed, 20 citations in OpenAlex.
- Giant Isotope Effect in Metal-Organic Frameworks Boosts Unprecedented Photo- and Radio-Luminescence Enhancement.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Unraveling the Growth Mechanism of Chiral Inorganic Nanocrystals via High-Resolution Electron Microscopy.Journal of the American Chemical Society · 2024Article
- Microenvironment regulation breaks the Faradaic efficiency-current density trade-off for electrocatalytic deuteration using DNature communications · 2024Article
- Switching molecular recognition selectivities by temperature in a diffusion-regulatory porous material.Nature communications · 2024Article
- Circularly polarized and total luminescence as probes of nucleation and growth in chiral nanocrystals.Chirality · 2023Article
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Mechanisms of nucleation and growth of crystals are still attracting a great deal of interest, in particular with recent advances in experimental techniques aimed at studying such phenomena. Studies of kinetic isotope effects in various reactions have been useful for elucidating reaction mechanisms, and it is believed that the same may apply for crystal formation kinetics. In this work, we present a kinetic study of the formation of europium-doped terbium phosphate nanocrystals under acidic conditions, including a strong H/D isotope effect. The nanocrystal growth process could be quantitatively followed through monitoring of the europium luminescence intensity. Hence, such lanthanide-based nanocrystals may serve as unique model systems for studying crystal nucleation and growth mechanisms. By combining the luminescence and NMR kinetics data, we conclude that the observed delayed nucleation occurs due to initial formation of pre-nucleation clusters or polymers of the lanthanide and phosphate ions, which undergo a phase transformation to crystal nuclei and further grow by cluster attachment. A scaling behavior observed on comparison of the H
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