Evidence map›Paper›PMID 35587213›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Stereocontrolled Pericyclic and Radical Cycloaddition Reactions of Readily Accessible Chiral Alkenyl Diazaborolidines.

Mingkai Zhang, Peilin Xu, Alex J Vendola, Christophe Allais, Anne-Marie Dechert Schmitt, Robert A Singer, James P Morken

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Mingkai ZhangDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467, USA.ORCID http://orcid.org/0000-0001-5343-1742
Peilin XuDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467, USA.ORCID http://orcid.org/0000-0002-7077-6096
Alex J VendolaDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467, USA.ORCID http://orcid.org/0000-0002-6309-7028
Christophe AllaisPfizer Worldwide Research and Development, Eastern Point Road, Groton, CT 06430, USA.ORCID http://orcid.org/0000-0002-3443-9391
Anne-Marie Dechert SchmittPfizer Worldwide Research and Development, Eastern Point Road, Groton, CT 06430, USA.ORCID http://orcid.org/0000-0002-2489-514X
Robert A SingerPfizer Worldwide Research and Development, Eastern Point Road, Groton, CT 06430, USA.ORCID http://orcid.org/0000-0001-9730-1261
James P MorkenDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467, USA.ORCID http://orcid.org/0000-0002-9123-9791

Funding

New Strategies in Catalytic Organic Synthesis with Organoboron ReagentsR35GM127140 · NIGMS · BOSTON COLLEGE · PI JAMES Patrick MORKEN · 2018 to 2026
$5.1M
NIGMS NIH HHS GM-R35-127140NIGMS NIH HHS R35 GM127140
6 · The paper itself

Abstract

In this paper is described an easily synthesized chiral diazaborolidine that is inexpensive, stable, and provides excellent stereoselection across a number of reaction classes. These versatile compounds possess utility in four different classes of cycloaddition reactions, offering good yield and stereoselectivity. X-ray structure analysis provides insight about the origin of stereocontrol.

Indexed as

BoronCycloadditionPhotoredox CatalysisStereoselectivity

Identifiers

PMID35587213
PMCPMC9296615

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.