ArticleInorganic chemistry2022
Investigating the Effect of Steric Hindrance within CdS Single-Source Precursors on the Material Properties of AACVD and Spin-Coat-Deposited CdS Thin Films.
Article in Inorganic chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Passivation, phase, and morphology control of CdS nanocrystals probed using fluorinated aromatic amines and solid-state NMR spectroscopy.Nanoscale advances · 2025Article
- Semiconductor Deposition via Laser Printing of a Bespoke Toner Containing Metal Xanthate Complexes.ACS applied engineering materials · 2024Article
- Synthetic Strategies toward High Entropy Materials: Atoms-to-Lattices for Maximum Disorder.Crystal growth & design · 2023Review
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Authors and funding
8 authors.
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Abstract
Cadmium sulfide (CdS) is an important semiconductor for electronic and photovoltaic applications, particularly when utilized as a thin film for window layers in CdTe solar cells. Deposition of thin-film CdS through the decomposition of single-source precursors is an attractive approach due to the facile, low-temperature, and rapid nature of this approach. Tailoring the precursor to affect the decomposition properties is commonly employed to tune desirable temperatures of decomposition. However, altering the precursor structure and the effect this has on the nature of the deposited material is an area far less commonly investigated. Here, we seek to investigate this by altering the ligands around the Cd metal center to increase the steric hindrance of the precursor and investigate the effect this has on the decomposition properties and the properties of deposited thin-film CdS from these precursors. For this, we report the synthesis of four CdS precursors with xanthate and pyridyl ligands ([Cd(
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