ArticleLight, science & applications2022
Direct demonstration of triplet excimer in purely organic room temperature phosphorescence through rational molecular design.
Article in Light, science & applications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- A new platform for achieving long-term air-stable long persistent luminescence in amorphous organic system.Light, science & applications · 2026Article
- Polymorph-Dependent Photophysics of Blue-Emitting Brominated Organic Crystals.ACS applied optical materials · 2026Article
- Ultrasound-responsive phosphorescence in aqueous solution enabled by microscale rigid framework engineering of carbon nanodots.Light, science & applications · 2025Article
- Ultralong organic afterglow from small molecular host-guest materials: state of the art.Light, science & applications · 2025Review
- Accurately adjusted phenothiazine conformations: reversible conformation transformation at room temperature and self-recoverable stimuli-responsive phosphorescence.Light, science & applications · 2025Article
- Enabling Aqueous Phase Long-lived Deep-blue Phosphorescence With Layered Double Hydroxide.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Visible-light-excited robust room-temperature phosphorescence of dimeric single-component luminophores in the amorphous state.Nature communications · 2024Article
- Controllable π-π coupling of intramolecular dimer models in aggregated states.Chemical science · 2024Article
- Management of triplet excitons transition: fine regulation of Förster and dexter energy transfer simultaneously.Light, science & applications · 2024Article
- Correlating structure and photophysical properties in thiazolo[5,4-Materials advances · 2023Article
- Photoactivated organic phosphorescence by stereo-hindrance engineering for mimicking synaptic plasticity.Light, science & applications · 2023Article
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Organic luminogens with room temperature phosphorescence (RTP) have been paid great attention and developed rapidly for their wide application values. Until now, the internal mechanism and source of phosphorescence are still obscure, especially for the relationship between molecular dimer and RTP emission. Hence, we designed and synthesized eight phenothiazine 5,5-dioxide derivatives to directly reveal how the monomer and dimer in packing affect the RTP behavior. Dimers with strong π-π stacking (θ < 20.66°; d < 3.86 Å) lead to pure triplet excimer emission, while those with weak π-π stacking (27.02°< θ < 40.64°; 3.84 Å < d < 4.41 Å) contribute to dual RTP emissions of both monomer and triplet excimer. The valuable information of this work would promote the further development of this research field, as well as others in aggregate.
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Registered trials
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