ArticleACS macro letters2022
Cascade Alternating Metathesis Cyclopolymerization of Diynes and Dihydrofuran.
Article in ACS macro letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. It is linked to trial NCT07023536 (Evaluation of the Effectiveness of a Cardiac Telerehabilitation Program in Chronic Heart Failure), which is not on this map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Evaluation of the Effectiveness of a Cardiac Telerehabilitation Program in Chronic Heart Failure
Who cites it
8 citing papers in PubMed.
- Exposure dose-dependent multi-tone photolithography via photoacid-induced crosslinking and degradation of poly(2,3-dihydrofuran).Nature communications · 2026Article
- Degradable polymers via controlled alternating ring-opening metathesis copolymerization of bio-sourced oxa-norbornenes and 2,3-dihydrofuran.Communications chemistry · 2026Article
- Chiral poly(aza-norbornene) derivatives with tunable tacticity and living ROMP capability.Chemical science · 2026Article
- Disubstituted Meldrum's Acid: Another Scaffold with SuFEx-like Reactivity.Molecules (Basel, Switzerland) · 2025Article
- Ring-Opening Metathesis Polymerization of Levoglucosenone-Derived Enyne Monomers.Journal of polymer science (2020) · 2025Article
- 3,6-Anhydrogalactal as a Single-Addition Monomer for Chain-End Functionalization of Metathesis Polymers.Journal of the American Chemical Society · 2025Article
- Highly Strained Tricyclic Oxanorbornenes with Uncommon Reactivity Enable Rapid ROMP for Thermally High-Performing Polyenes.Macromolecules · 2025Article
- Ring-Opening Metathesis Polymerization of 1,2-Dihydroazete Derivatives.Angewandte Chemie (International ed. in English) · 2025Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Ruthenium alkoxymethylidene complexes have recently come into view as competent species for metathesis copolymerization reactions when coupled with appropriate comonomer targets. Here, we explore the ability of Fischer-type carbenes to participate in cascade alternating metathesis cyclopolymerization (CAMC) through facile terminal alkyne addition. The combination of diyne monomers and an equal feed ratio of low-strain dihydrofuran leads to a controlled chain-growth copolymerization with high degrees of alternation (>97% alternating diads) and produces degradable polymer materials with low dispersities and targetable molecular weights. When combined with enyne monomers, this method is amenable to the synthesis of alternating diblock copolymers that can be fully degraded to short oligomer fragments under aqueous acidic conditions. This work furthers the potential for the generation of functional metathesis materials via Fischer-type ruthenium alkylidenes.
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Registered trials
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