Evidence map›Paper›PMID 35566131›Full record

ArticleMolecules (Basel, Switzerland)2022

Polyoxometalate/Cellulose Nanofibrils Aerogels for Highly Efficient Oxidative Desulfurization.

Rui Song, Xueqin Zhang, Huihui Wang, Chuanfu Liu

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Rui SongState Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510006, China.
Xueqin ZhangCollege of Light Industry and Food Science, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, China.
Huihui WangState Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510006, China.
Chuanfu LiuState Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510006, China.ORCID 0000-0002-3151-7956

Funding

China Postdoctoral Science Foundation 2019TQ0102Foundation and Applied Foundation Research Project of Guangdong Province 2019A1515110191National Key Research and Development Program of China 2021YFC2101604National Natural Science Foundation of China 32001279Science and Technology Basic Resources Investigation Program of China 2019FY100900
6 · The paper itself

Abstract

Polyoxometalate (POM) presents great potential in oxidative desulfurization (ODS) reaction. However, the high dissolubility of POM in common solvents makes it difficult to recycle. Besides, the small specific surface area of POM also limits the interaction between them and the substrate. Depositing polyoxometalates onto three-dimensional (3D) network structured materials could largely expand the application of POM. Here, the surfaces of cellulose nanofibrils (CNFs) were modified with very few (3-Aminopropyl) trimethoxysilane (APTS) to endow positive charges on the surfaces of CNFs, and then phosphotungstic acid (PTA) was loaded to obtain the aerogel A-CNF/PTA as the ODS catalyst. FT-IR indicated the successful deposition of PTA onto aminosilane modified CNF surfaces. UV-VIS further suggested the stability of PTA in the aerogels. BET and SEM results suggested the increased specific surface area and the relatively uniform 3D network structure of the prepared aerogels. TGA analysis indicated that the thermal stability of the aerogel A-CNF/PTA50% was a little higher than that of the pure CNF aerogel. Most importantly, the aerogel A-CNF/PTA50% showed good catalytic performance for ODS. Catalysis results showed that the substrate conversion rate of the aerogel A-CNF/PTA50% reached 100% within 120 min at room temperature. Even after five cycles, the substrate conversion rate of the aerogel A-CNF/PTA50% still reached 91.2% during the dynamic catalytic process. This work provides a scalable and facile way to stably deposit POM onto 3D structured materials.

Indexed as

CelluloseNanofibersAnionsOxidative StressPolyelectrolytesPolyoxometalatesSpectroscopy, Fourier Transform InfraredAnionsCellulosePolyelectrolytesPolyoxometalatescatalystcellulose nanofibrilsoxidation desulfurizationphosphotungstic acid

Identifiers

PMID35566131
PMCPMC9101072

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.