ArticleInternational journal of molecular sciences2022
Mathematical Modeling of Monovalent Permselectivity of a Bilayer Ion-Exchange Membrane as a Function of Current Density.
Article in International journal of molecular sciences, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Separation of Chloride and Sulfate Ions from Desulfurization Wastewater Using Monovalent Anions Selective Electrodialysis.Membranes · 2024Article
- Cation Exchange Membranes and Process Optimizations in Electrodialysis for Selective Metal Separation: A Review.Membranes · 2023Review
- Ion and Molecule Transport in Membrane Systems 3.0 and 4.0.International journal of molecular sciences · 2023Article
- Selective Separation of Singly Charged Chloride and Dihydrogen Phosphate Anions by Electrobaromembrane Method with Nanoporous Membranes.Membranes · 2023Article
- Ion and Water Transport in Ion-Exchange Membranes for Power Generation Systems: Guidelines for Modeling.International journal of molecular sciences · 2022Review
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Authors and funding
3 authors.
Funding
Abstract
Modification of an ion-exchange membrane with a thin layer, the charge of which is opposite to the charge of the substrate membrane, has proven to be an effective approach to obtaining a composite membrane with permselectivity towards monovalent ions. However, the mechanism of permselectivity is not clear enough. We report a 1D model based on the Nernst-Planck-Poisson equation system. Unlike other similar models, we introduce activity coefficients, which change when passing from one layer of the membrane to another. This makes it possible to accurately take into account the fact that the substrate membranes usually selectively sorb multiply charged counterions. We show that the main cause for the change in the permselectivity coefficient,
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