ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Lewis Acid Assisted Brønsted Acid Catalysed Decarbonylation of Isocyanates: A Combined DFT and Experimental Study.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Allylic Hydrogen Acidity of 1-Butene Derivatives Coordinated to Transition Metals─A Mechanistic Insight Including Carbonyl-Olefin Metathesis.Inorganic chemistry · 2025Article
- Paving the Way towards Sustainability of Polyurethanes: Synthesis and Properties of Terpene-Based Diisocyanate.Molecules (Basel, Switzerland) · 2023Article
- Lewis Acid Assisted Brønsted Acid Catalysed Decarbonylation of Isocyanates: A Combined DFT and Experimental Study.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
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Authors and funding
8 authors.
Funding
Abstract
An efficient and mild reaction protocol for the decarbonylation of isocyanates has been developed using catalytic amounts of Lewis acidic boranes. The electronic nature (electron withdrawing, electron neutral, and electron donating) and the position of the substituents (ortho/meta/para) bound to isocyanate controls the chain length and composition of the products formed in the reaction. Detailed DFT studies were undertaken to account for the formation of the mono/di-carboxamidation products and benzoxazolone compounds.
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