ArticleRSC advances2018
Glycol-functionalized ionic liquids for high-temperature enzymatic ring-opening polymerization.
Article in RSC advances, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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Who cites it
4 citing papers in PubMed.
- Functionalized Ionic Liquids for COGreen chemistry letters and reviews · 2023Article
- Recent Advances in the Enzymatic Synthesis of Polyester.Polymers · 2022Review
- Prospects of Using Biocatalysis for the Synthesis and Modification of Polymers.Molecules (Basel, Switzerland) · 2021Review
- Article
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Authors and funding
4 authors.
Funding
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Abstract
Enzymatic ring-opening polymerization (ROP) is a benign method for preparing polyesters, such as polylactides and other polylactones. These reactions are typically carried out at relatively high temperatures (60-130 °C), however, there is a deficiency of enzyme-compatible solvents for such thermally-demanding biocatalytic processes. In this study, we have prepared a series of short-chained glycol-grafted ionic liquids (ILs) based on a phosphonium, imidazolium, pyridinium, ammonium, or piperidinium cationic headgroup. Most of these glycol-grafted ILs exhibit relatively low dynamic viscosities (33-123 mPa s at 30 °C), coupled with excellent short-term thermal stabilities with decomposition temperatures (
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Registered trials
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