ArticleJACS Au2022
Mechanistic Insight into the Precursor Chemistry of ZrO
Article in JACS Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 11 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
11 citing papers in PubMed, 18 citations in OpenAlex.
- Ligand Electronic Properties Dictate Composition of Ni-Based Nanocrystals.Journal of the American Chemical Society · 2025Article
- Prospects of Nanoscience with Nanocrystals: 2025 Edition.ACS nano · 2025Review
- From Kinetics to Molecular-Level Insights into Group 4 Metal Oxide Nanocrystal Synthesis.ACS materials Au · 2025Article
- Local orthorhombic phase in zirconium oxide nanocrystals: insights from X-ray pair distribution function analysis.Journal of applied crystallography · 2025Article
- Epitaxial Core/Shell Nanocrystals of (Europium-Doped) Zirconia and Hafnia.Journal of the American Chemical Society · 2024Article
- Synthesis of zirconium(IV) and hafnium(IV) isopropoxide,Dalton transactions (Cambridge, England : 2003) · 2024Article
- Complexation and disproportionation of group 4 metal (alkoxy) halides with phosphine oxides.Dalton transactions (Cambridge, England : 2003) · 2024Article
- From Gel to Crystal: Mechanism of HfOJournal of the American Chemical Society · 2024Article
- Tailoring of Colloidal HfOSmall science · 2024Article
- An Amorphous Phase Precedes Crystallization: Unraveling the Colloidal Synthesis of Zirconium Oxide Nanocrystals.ACS nano · 2023Article
- Fatty acid capped, metal oxo clusters as the smallest conceivable nanocrystal prototypes.Chemical science · 2023Article
Corrections and comments
- Erratum issued
Authors and funding
10 authors at 3 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
One can nowadays readily generate monodisperse colloidal nanocrystals, but a retrosynthetic analysis is still not possible since the underlying chemistry is often poorly understood. Here, we provide insight into the reaction mechanism of colloidal zirconia and hafnia nanocrystals synthesized from metal chloride and metal isopropoxide. We identify the active precursor species in the reaction mixture through a combination of nuclear magnetic resonance spectroscopy (NMR), density functional theory (DFT) calculations, and pair distribution function (PDF) analysis. We gain insight into the interaction of the surfactant, tri-
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.