ArticleJACS Au2022
Excited-State Dynamics of Crossing-Controlled Energy Transfer in Europium Complexes.
Article in JACS Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Ligand triplet energy escape in lanthanide complexes for developing luminescent molecular thermometers.Communications chemistry · 2025Article
- Role of Vibronic Coupling for the Dynamics of Intersystem Crossing in EuJournal of chemical theory and computation · 2025Article
- An enzyme/pH dual-responsive supramolecular fluorescent vesicle with tunable size fabricated by europium complex and polypseudorotaxanes.Scientific reports · 2025Article
- Unearthing the Real-Time Excited State Dynamics from Antenna to Rare Earth Ions Using Ultrafast Transient Absorption.JACS Au · 2024Article
- Full Picture of Energy Transfer in a Trivalent Europium Complex with Bidentate β-Diketonate Ligand.The journal of physical chemistry letters · 2024Article
- Deciphering intersystem crossing and energy transfer mechanisms in a nonacoordinated ternary europium(iii) complex: a combined spectroscopic and theoretical study.RSC advances · 2024Article
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Authors and funding
11 authors.
Funding
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Abstract
Photosensitized energy transfer (EnT) phenomena occur frequently in a variety of photophysical and photochemical processes and have traditionally been treated with the donor-acceptor distance-dependent Förster and Dexter models. However, incorrect arguments and formulae were employed by ignoring energy resonance conditions and the selection rules of the state-to-state transition in special cases, especially for the sensitive intramolecular EnT of lanthanide complexes. Herein, we proposed an innovative model of energy-degeneracy-crossing-controlled EnT, which can be experimentally confirmed by time-resolved two-dimensional photoluminescence measurements. The computationally determined energy resonance region provides the most effective channel to achieve metal-to-ligand EnT beyond the distance-dependent model and sensitively bifurcates into symmetry-allowed or -forbidden channels for some representative europium antenna complexes. The outcomes of the multidisciplinary treatment contribute to a complementary EnT model that can be tuned by introducing a phosphorescence modulator and altering the antenna-related parameters of the ligand-centered energy level of the
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Registered trials
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