Evidence map›Paper›PMID 35548924›Full record

ArticleChemical communications (Cambridge, England)2022

Diastereoselective additions of H-phosphinates to alkenyl ketones under phase-transfer conditions.

Krishna P Yadavalli, Johannah E Cummines, Chace J Carlisle, Salvatore D Lepore

Abstract read
In one paragraph

Article in Chemical communications (Cambridge, England), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Krishna P YadavalliDepartment of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, FL, 33431-0991, USA. slepore@fau.edu.
Johannah E CumminesDepartment of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, FL, 33431-0991, USA. slepore@fau.edu.
Chace J CarlisleDepartment of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, FL, 33431-0991, USA. slepore@fau.edu.
Salvatore D LeporeDepartment of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, FL, 33431-0991, USA. slepore@fau.edu.ORCID http://orcid.org/0000-0002-8824-6114

Funding

Synthesis of a Bridged Bicyclic Natural Product Using Allenyl EstersR15GM110651 · NIGMS · FLORIDA ATLANTIC UNIVERSITY · PI LEPORE, SALVATORE D · 2014 to 2020
$1.2M
NIGMS NIH HHS R15 GM110651
6 · The paper itself

Abstract

Additions of bulky H-phosphinates to β,β-disubstituted alkenyl ketones under the action of a phase transfer-catalyst led to a new class of carbon quaternary center-containing phosphinates with unprecedented control of the relative configuration of the adjacent carbon and phosphorous chiral centers with high diastereoselectivity in most cases.

Indexed as

CarbonKetonesCatalysisStereoisomerismCarbonKetones

Identifiers

PMID35548924
PMCPMC9365031

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.