Evidence map›Paper›PMID 35541005›Full record

ReviewRSC advances2018

Combining transition metals and transient directing groups for C-H functionalizations.

Trisha Bhattacharya, Sandeep Pimparkar, Debabrata Maiti

Abstract readReview
In one paragraph

Review in RSC advances, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.

0numbers the graph read from it
0cells of the map it votes in
18citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

18 citing papers in PubMed.

  1. Article
  2. Palladium-CatalyzedMolecules (Basel, Switzerland) · 2024
    Article
  3. Review
  4. Article
  5. Review
  6. OvercomingChemical science · 2022
    Article
  7. Review
  8. Review
  9. Article
  10. Review
  11. Review
  12. Article
  13. Article
  14. Review
  15. Peptide late-stage C(spChemical science · 2020
    Article
  16. Review
  17. Article
  18. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Trisha BhattacharyaDepartment of Chemistry, IIT Bombay Powai Mumbai-400076 India dmaiti@chem.iitb.ac.in.
Sandeep PimparkarDepartment of Chemistry, IIT Bombay Powai Mumbai-400076 India dmaiti@chem.iitb.ac.in.
Debabrata MaitiDepartment of Chemistry, IIT Bombay Powai Mumbai-400076 India dmaiti@chem.iitb.ac.in.ORCID https://orcid.org/0000-0001-8353-1306

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In the domain of synthetic chemistry, C-H bond activation has always remained in the spotlight for researchers over the last few decades. Although different strategies have been employed to chemically trigger unactivated C-H bonds, transition metal catalyzed directing group (DG) aided C-H bond activation is the most explored pathway of all because of its ability to perform diverse site selective functional metamorphosis. Despite its popularity, tedious synthetic methodology requiring additional steps for the installation and removal of DGs from the target substrate diminishes its efficacy. However, replacement of directing groups by transient directing groups (tDGs) reduces the hurdle to a greater extent without compromising the product yield and selectivity. In this report we have depicted the intense journey of transient directing groups with three (Rh, Ru, and Pd) prevalent second row transition metals.

Identifiers

PMID35541005
PMCPMC9080754

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.