ArticleRSC advances2019
Tailoring intermolecular interactions to develop a low-temperature electrolyte system consisting of 1-butyl-3-methylimidazolium iodide and organic solvents.
Article in RSC advances, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Fluorinated Carboxylic Acid Ester and Carbonate Solvent Synergistically Improve Low-Temperature Performance of LiFePOChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Correlation Analysis of TSB Level and Globus Pallidus-Related Metabolite Indexes of Proton Magnetic Resonance Spectroscopy in the Newborn with Neonatal Jaundice.Evidence-based complementary and alternative medicine : eCAM · 2022Article
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6 authors.
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Abstract
Ionic liquids (ILs) exhibit remarkable properties and great tunability, which make them an attractive class of electrolyte materials for a variety of electrochemical applications. However, despite the promising progress for operating conditions at high temperatures, the development of their low-temperature viability as electrolytes is still limited due to the constrains from thermal and ion transport issues with a drastic decrease in temperature. In this study, we present a liquid electrolyte system based on a mixture of 1-butyl-3-methylimidazolium iodide ([BMIM][I]), γ-butyrolactone (GBL), propylene carbonate (PC), and lithium iodide (LiI) and utilize its molecular interactions to tailor its properties for extremely low-temperature sensing applications. In particular, the carbonyl group on both PC and GBL can form hydrogen bonds with the imidazolium cation, as indicated by Fourier transform infrared spectroscopy (FTIR), and the extent of these interactions between ions and molecules was also characterized and quantified
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