Evidence map›Paper›PMID 35534509›Full record

ArticleNature communications2022

Direct and real-time observation of hole transport dynamics in anatase TiO

Sang Han Park, Abhishek Katoch, Keun Hwa Chae, Sanjeev Gautam, Piter Miedema, Sang Wan Cho, Minseok Kim, Ru-Pan Wang, Masoud Lazemi, Frank de Groot and 1 more

Abstract read
In one paragraph

Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed.

  1. Article
  2. Article
  3. Ultrafast Light-Driven Electronic and Structural Changes in LaFeOAdvanced materials (Deerfield Beach, Fla.) · 2025
    Article
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Synthesis and Characterization of N and Fe-Doped TiONanomaterials (Basel, Switzerland) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Sang Han ParkPohang Accelerator Laboratory, Pohang, Gyeongbuk, 37673, South Korea.
Abhishek KatochPohang Accelerator Laboratory, Pohang, Gyeongbuk, 37673, South Korea.
Keun Hwa ChaeKorea Institute of Science and Technology, Seoul, South Korea.ORCID http://orcid.org/0000-0003-3894-670X
Sanjeev GautamDr S. S. Bhatnagar University Institute of Chemical Engineering & Technology, Panjab University, Chandigarh, 160014, India.ORCID http://orcid.org/0000-0003-3123-9906
Piter MiedemaEuropean XFEL Gmbh, Notkestrasse 85, D-22607, Hamburg, Germany.ORCID http://orcid.org/0000-0003-1959-3216
Sang Wan ChoDepartment of Physics, Yonsei Univerity, Wonju, South Korea.ORCID http://orcid.org/0000-0001-7258-8059
Minseok KimPohang Accelerator Laboratory, Pohang, Gyeongbuk, 37673, South Korea.
Ru-Pan WangMaterials Chemistry and Catalysis (MCC), Debye Institute for Nanomaterials Science, Utrecht University, Universiteitslaan 99, 3584 CG, Utrecht, The Netherlands.ORCID http://orcid.org/0000-0003-4495-9881
Masoud LazemiMaterials Chemistry and Catalysis (MCC), Debye Institute for Nanomaterials Science, Utrecht University, Universiteitslaan 99, 3584 CG, Utrecht, The Netherlands.
Frank de GrootMaterials Chemistry and Catalysis (MCC), Debye Institute for Nanomaterials Science, Utrecht University, Universiteitslaan 99, 3584 CG, Utrecht, The Netherlands. f.m.f.degroot@uu.nl.
Soonnam KwonPohang Accelerator Laboratory, Pohang, Gyeongbuk, 37673, South Korea. snkwon@postech.ac.kr.

Funding

National Research Foundation of Korea (NRF) NRF-2018R1D1A1B07046676National Research Foundation of Korea (NRF) NRF-2020R1A2C1007416
6 · The paper itself

Abstract

Carrier dynamics affects photocatalytic systems, but direct and real-time observations in an element-specific and energy-level-specific manner are challenging. In this study, we demonstrate that the dynamics of photo-generated holes in metal oxides can be directly probed by using femtosecond X-ray absorption spectroscopy at an X-ray free-electron laser. We identify the energy level and life time of holes with a long life time (230 pico-seconds) in nano-crystal materials. We also observe that trapped holes show an energy distribution in the bandgap region with a formation time of 0.3 pico-seconds and a decay time of 8.0 pico-seconds at room temperature. We corroborate the dynamics of the electrons by using X-ray absorption spectroscopy at the metal L-edges in a consistent explanation with that of the holes.

Identifiers

PMID35534509
PMCPMC9085873

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.