ArticleRSC advances2022
Mechanistic insights into rare-earth-catalysed C-H alkylation of sulfides: sulfide facilitating alkene insertion and beyond.
Article in RSC advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Titanium-Catalyzed Intermolecular Hydrothiomethylation of Alkenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Regioselective C-H alkylation of anisoles with olefins by cationic imidazolin-2-iminato scandium(iii) alkyl complexes.Chemical science · 2023Article
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7 authors.
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Abstract
The catalytic C-H alkylation with alkenes is of much interest and importance, as it offers a 100% atom efficient route for C-C bond construction. In the past decade, great progress in rare-earth catalysed C-H alkylation of various heteroatom-containing substrates with alkenes has been made. However, whether or how a heteroatom-containing substrate would influence the coordination or insertion of an alkene at the catalyst metal center remained elusive. In this work, the mechanism of Sc-catalysed C-H alkylation of sulfides with alkenes and dienes has been carefully examined by DFT calculations, which revealed that the alkene insertion could proceed
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