ArticleRSC advances2020
Supramolecular thermogels from branched PCL-containing polyurethanes.
Article in RSC advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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Who cites it
5 citing papers in PubMed, 13 citations in OpenAlex.
- Article
- Designing MOF-Thermogel Nanocomposites for Differential Multidrug Release in Combination Cancer Therapy.ACS applied nano materials · 2025Article
- Near-Infrared Dye-Loaded Thermosensitive Hydrogels as Novel Fluorescence Tissue Markers.Gels (Basel, Switzerland) · 2025Article
- Thermo-Responsive Hydrogels: From Recent Progress to Biomedical Applications.Gels (Basel, Switzerland) · 2021Review
- Toward the prevention of coronavirus infection: what role can polymers play?Materials today. Advances · 2021Review
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Thermogels are temperature-responsive hydrogels which are most commonly formed by supramolecular self-assembly of polymer amphiphiles comprising of both hydrophobic and hydrophilic segments. Although polyurethane thermogels have shown great promise as biomaterials, their synthesis by step-growth polymerisation of diols and diisocyanates can also result in formation of allophanate branches, which arise from the reaction between free isocyanate groups and urethane linkages along the polymer backbone. In this paper, we investigate the effects of different synthetic conditions on the degree of allophanate branching on polyurethane amphiphiles, and explore the influences of these branches on the polymers' critical micelle concentration (CMC), thermodynamics of micellization and subsequent thermogel properties. Our findings offer new insights into the relationship between polymer structure, micelle and gel properties. These results highlight the importance of taking polymer branching into account for understanding the hierarchical self-assembly of polymer amphiphiles and the resulting thermogel properties and behaviour.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.