Evidence map›Paper›PMID 35516574›Full record

ArticleRSC advances2020

Construction of fluorescence active MOFs with symmetrical and conformationally rigid

Jingyang Li, Ying He, Li Wang, Guanghua Li, Yongcun Zou, Yan Yan, Dandan Li, Xinli Shi, Zhiguang Song, Xiaodong Shi

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in RSC advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Jingyang LiState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 13002 China szg@jlu.edu.cn.
Ying HeDepartment of Chemistry, University of South Florida 4202 E. Fowler Avenue Tampa Florida 33620 USA xmshi@usf.edu.
Li WangState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 13002 China szg@jlu.edu.cn.ORCID https://orcid.org/0000-0003-3923-4384
Guanghua LiState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 13002 China szg@jlu.edu.cn.
Yongcun ZouState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 13002 China szg@jlu.edu.cn.
Yan YanState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 13002 China szg@jlu.edu.cn.
Dandan LiState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 13002 China szg@jlu.edu.cn.ORCID https://orcid.org/0000-0003-2824-4130
Xinli ShiState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 13002 China szg@jlu.edu.cn.
Zhiguang SongState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 13002 China szg@jlu.edu.cn.
Xiaodong ShiDepartment of Chemistry, University of South Florida 4202 E. Fowler Avenue Tampa Florida 33620 USA xmshi@usf.edu.ORCID https://orcid.org/0000-0002-3189-1315

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

1,4-Bis-triazole-substituted arene (NAT) was designed and synthesized for the construction of metal organic frameworks. Unlike the tri-phenyl analogs, which give a twisted conformation between three benzene rings due to the A-1,3 repulsion, the NAT-ligand gave the energetically favored co-planar conformation with the strong fluorescence emission. With this ligand, two new MOFs, NAT-MOF-Cd (2,3,4-c) and NAT-MOF-Cu (4-c), were successfully obtained with the structure confirmed by X-ray. With the six-coordinated Cd(ii) cluster, an interesting metal-ligand coordination and H-bonding hybridized porous polymeric structures were observed. In contrast, a typical Cu(ii) paddle wheel coordination was obtained with NAT and Cu, giving a new MOF structure with moderate stability in aqueous solution from pH 1-11 for 24 hours, which suggests a promising future for applications in fluorescence sensing and photocatalysis.

Identifiers

PMID35516574
PMCPMC9057867

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