ArticleRSC advances2020
Sustainable access to fully biobased epoxidized vegetable oil thermoset materials prepared by thermal or UV-cationic processes.
Article in RSC advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed, 62 citations in OpenAlex.
- Carboxylic Acid-Cured Epoxidised Soybean Oil under Catalyst-Free Conditions: Kinetics and Sustainable Packaging Potential.ACS omega · 2026Article
- Thermally Regulated Curing-Degradation Windows of Epoxidized Soybean Oil-Based Epoxy-Anhydride Liquid Plugs for Sustainable High-Temperature Sealing.Molecules (Basel, Switzerland) · 2026Article
- Bio-Based, Degradable, and Tunable Epoxy Thermosets from Homogenized Acids and Epoxidized Linseed Oil or Glycerol Triglycidyl Ether.ACS sustainable chemistry & engineering · 2026Article
- Sustainable base oils from non-edible fats: performance of esterified, epoxidized, and hydroxylated brown grease.RSC advances · 2025Article
- Direct Acrylation of Soybean Oil and the Influence of the Acrylation Degree on Waterborne Acrylic Systems.Polymers · 2024Article
- Thermo-Responsive Shape-Memory Dual-Cured Polymers Based on Vegetable Oils.Materials (Basel, Switzerland) · 2023Article
- One-Step Method for Direct Acrylation of Vegetable Oils: A Biobased Material for 3D Printing.Polymers · 2023Article
- Biobased epoxy reactive diluents prepared from monophenol derivatives: effect on viscosity and glass transition temperature of epoxy resins.RSC advances · 2023Article
- Article
- Aquivion perfluorosulfonic superacid as an effective catalyst for selective epoxidation of vegetable oils.Royal Society open science · 2022Article
- Synthesis of non-phosphorylated epoxidised corn oil as a novel green flame retardant thermoset resin.Scientific reports · 2021Article
- Mechanical Properties of Hybrid Carbonized Plant Fibers Reinforced Bio-Based Epoxy Laminates.Polymers · 2021Article
- Cationic UV-Curing of Epoxidized Biobased Resins.Polymers · 2020Review
Corrections and comments
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Authors and funding
6 authors at 3 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Beyond the need to find a non-toxic alternative to DiGlycidyl Ether of Bisphenol-A (DGEBA), the serious subject of non-epichlorohydrin epoxy resins production remains a crucial challenge that must be solved for the next epoxy resin generations. In this context, this study focuses on the valorization of vegetable oils (VOs) into thermoset materials by using (i) epoxidation of the VOs through the "double bonds to epoxy" synthetic route and (ii) synthesis of crosslinked homopolymers by UV or hardener-free thermal curing processes. A thorough identification, selection and physico-chemical characterization of non-edible or non-valuated natural vegetable oils were performed. Selected VOs, characterized by a large range of double bond contents, were then chemically modified into epoxides thanks to an optimized, robust and sustainable method based on the use of acetic acid, hydrogen peroxide and Amberlite® IR-120 at 55 °C in toluene or cyclopentyl methyl ether (CMPE) as a non-hazardous and green alternative solvent. The developed environmentally friendly epoxidation process allows reaching almost complete double bond conversion with an epoxy selectivity above 94% for the 12 studied VOs. Finally, obtained epoxidized vegetable oils (EVOs), characterized by an epoxy index from 2.77 to 6.77 m
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.