ArticleRSC advances2020
Retracted Article: Metal-free [2+2+1] cycloaddition polymerization of alkynes, nitriles, and oxygen atoms to functional polyoxazoles.
Article in RSC advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. It has been retracted, and should not be counted. Not yet cited in PubMed.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
0 citing papers in PubMed, 4 citations in OpenAlex.
No citing paper in PubMed yet.
Corrections and comments
- Correction · 2021-01-11Error in Text · Updated to Retraction ·
- Retraction · 2021-04-30Concerns/Issues about Data · Concerns/Issues about Image · Unreliable Results and/or Conclusions · Upgrade/Update of Prior Notice(s) ·
- Erratum issued
- Retracted
Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The metal-free [2+2+1] cycloaddition polymerization of alkynes, nitriles, and O-atoms for the regioselective assembly of highly substituted oxazole compounds has been achieved by the use of iodosobenzene (PhIO) with trifluoromethanesulfonic acid (TfOH). The present reaction could be applied to a facile synthesis of polyoxazoles. In this work, the cycloaddition polymerization of 4-cyano-4'-ethynylbiphenyl and PhIO was developed and modified polyoxazole was prepared. All experimental conditions such as polymerization solvent, temperature, catalyst and time were systematically studied. The structure of the obtained polyoxazole was characterized by GPC and NMR, and its thermal properties were studied by TGA. In addition, the good thermal stability of polyoxazoles with unreacted terminal alkynes and cyano groups makes them potentially useful for modifying resins.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.