ArticleACS catalysis2022
Site-Selective Catalytic Epoxidation of Alkene with Tunable, Atomic Precision by Molecularly Imprinted Artificial Epoxidases.
Article in ACS catalysis, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
10 citing papers in PubMed, 22 citations in OpenAlex.
- Regioselective epoxidation of a polyunsaturated fatty acid by a vanadyl complex with redox-active ligands.Chemical communications (Cambridge, England) · 2026Article
- Confined Catalysis of Enzymes: Enhancement Strategies, Materials, and Biosensor Applications.Journal of functional biomaterials · 2026Review
- [Research progress in the application of molecular imprinting technology in catalysis].Se pu = Chinese journal of chromatography · 2026Article
- Research Progress in Epoxidation of Light Small-Molecule Olefins.Molecules (Basel, Switzerland) · 2025Review
- Enhanced molecular recognition with longer chain crosslinkers in molecularly imprinted polymers for an efficient separation of TR active substances.RSC advances · 2024Article
- Improving the Selectivity of the C-C Coupled Product Electrosynthesis by Using Molecularly Imprinted Polymer─An Enhanced Route from Phenol to Biphenol.ACS applied materials & interfaces · 2023Article
- Carbonic anhydrase mimics with rationally designed active sites for fine-tuned catalytic activity and selectivity in ester hydrolysis.Catalysis science & technology · 2023Article
- Supramolecular Regulation of Catalytic Activity in Molecularly Responsive Catalysts.The Journal of organic chemistry · 2023Article
- Acid-Functionalized Artificial Enzymes with Tunable Selectivity for Vinyl Ether Hydrolysis.The Journal of organic chemistry · 2023Article
- Synergistic Hydrolysis of Cellulose by a Blend of Cellulase-Mimicking Polymeric Nanoparticle Catalysts.Journal of the American Chemical Society · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
Distinction of chemical functionality by their local chemical environment is a skill mastered by enzymes, evident from the selective synthesis, cleavage, and transformation of peptides, nucleic acids, and polysaccharides that abound with the same type of functional groups. In contrast, synthetic catalysts are generally better at differentiating functional groups based on their electronic and steric properties. Here we report artificial epoxidases prepared through molecular imprinting of surface-core doubly cross-linked micelles, followed by efficient functionalization of the imprinted site in the micellar core via photoaffinity labeling. The size and shape of the active sites are tuned by the modularly synthesized templates, with the oxygen-delivering peroxy acid group positioned accurately. These catalysts are used in epoxidation of alkene in water with hydrogen peroxide under mild conditions, without any additional additives. Most importantly, atomic precision is achieved in the catalysis and enables alkenes to be distinguished that differ in the position of the carbon-carbon double bond by a single carbon.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.