Evidence map›Paper›PMID 35515801›Full record

ArticleRSC advances2020

Insight into the photophysics of strong dual emission (blue & green) producing graphene quantum dot clusters and their application towards selective and sensitive detection of trace level Fe

Ganapathi Bharathi, Devaraj Nataraj, Sellan Premkumar, Padmanaban Saravanan, Daniel T Thangadurai, Oleg Yu Khyzhun, Kittusamy Senthilkumar, Ramasamy Kathiresan, Ponmalai Kolandaivel, Mukul Gupta and 1 more

Abstract read
In one paragraph

Article in RSC advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Ganapathi BharathiQuantum Materials & Energy Devices (QM-ED) Laboratory, Department of Physics, Bharathiar University Coimbatore TN India de.natraj2011@gmail.com.
Devaraj NatarajQuantum Materials & Energy Devices (QM-ED) Laboratory, Department of Physics, Bharathiar University Coimbatore TN India de.natraj2011@gmail.com.ORCID https://orcid.org/0000-0002-4711-8263
Sellan PremkumarQuantum Materials & Energy Devices (QM-ED) Laboratory, Department of Physics, Bharathiar University Coimbatore TN India de.natraj2011@gmail.com.
Padmanaban SaravananDefence Metallurgical Research Laboratory Hyderabad 500 058 India.
Daniel T ThangaduraiDepartment of Nanoscience and Technology, Sri Ramakrishana Engineering College, Affiliated to Anna University Coimbatore - 641 022 TN India.
Oleg Yu KhyzhunDepartment of Structural Chemistry of Solids, Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine UA-03142 Kyiv Ukraine.ORCID https://orcid.org/0000-0002-2403-8607
Kittusamy SenthilkumarUGC-CPEPA Centre for Advanced Studies in Physics for the Development of Solar Energy Materials and Devices, Department of Physics, Bharathiar University Coimbatore TN India.ORCID https://orcid.org/0000-0002-3420-8163
Ramasamy KathiresanMacromolecular Laboratory, Department of Physics, Bharathiar University Coimbatore TN India.
Ponmalai KolandaivelMacromolecular Laboratory, Department of Physics, Bharathiar University Coimbatore TN India.
Mukul GuptaUGC-DAE Consortium for Scientific Research Indore MP India.ORCID https://orcid.org/0000-0002-9622-656X
Deodatta PhaseUGC-DAE Consortium for Scientific Research Indore MP India.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Graphene-nanostructured systems, such as graphene quantum dots (GQDs), are well known for their interesting light-emitting characteristics and are being applied to a variety of luminescence-based applications. The emission properties of GQDs are complex. Therefore, understanding the science of the photophysics of coupled quantum systems (like quantum clusters) is still challenging. In this regard, we have successfully prepared two different types of GQD clusters, and explored their photophysical properties in detail. By co-relating the structure and photophysics, it was possible to understand the emission behavior of the cluster in detail. This gave new insight into understanding the clustering effect on the emission behaviour. The results clearly indicated that although GQDs are well connected, the local discontinuity in the structure prohibits the dynamics of photoexcited charge carriers going from one domain to another. Therefore, an excitation-sensitive dual emission was possible. Emission yield values of about 18% each were recorded at the blue and green emission wavelengths at a particular excitation energy. This meant that the choice of emission color was decided by the excitation energy. Through systematic analysis, it was found that both intrinsic and extrinsic effects contributed to the blue emission, whereas only the intrinsic effect contributed to the green emission. These excitation-sensitive dual emissive GQD clusters were then used to sense Fe

Identifiers

PMID35515801
PMCPMC9055443

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.