ReviewPhysical chemistry chemical physics : PCCP2022
Photoionization of the aqueous phase: clusters, droplets and liquid jets.
Review in Physical chemistry chemical physics : PCCP, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Simulating the Photochemical Birth of the Hydrated Electron in Liquid Water.Nature communications · 2026Article
- Photoelectron imaging of substituted benzenes in aqueous aerosol droplets.Physical chemistry chemical physics : PCCP · 2026Article
- Article
- Core-Level Photoelectron Angular Distributions from Bulk-Solvated to Surface-Active Aqueous Potassium Carboxylate Salts.The journal of physical chemistry. B · 2025Article
- Valence Electronic Structure of Interfacial Phenol in Water Droplets.The journal of physical chemistry. A · 2024Article
- Liquid-jet photoemission spectroscopy as a structural tool: site-specific acid-base chemistry of vitamin C.Physical chemistry chemical physics : PCCP · 2024Article
- Valence photoelectron imaging of molecular oxybenzone.Physical chemistry chemical physics : PCCP · 2024Article
- X-ray radiation damage cycle of solvated inorganic ions.Nature communications · 2024Article
- Compression of a Stearic Acid Surfactant Layer on Water Investigated by Ambient Pressure X-ray Photoelectron Spectroscopy.The journal of physical chemistry. B · 2024Article
- Radiation damage by extensive local water ionization from two-step electron-transfer-mediated decay of solvated ions.Nature chemistry · 2023Article
- The Metal-Oxide Nanoparticle-Aqueous Solution Interface Studied by Liquid-Microjet Photoemission.Accounts of chemical research · 2023Article
- Imaging temperature and thickness of thin planar liquid water jets in vacuum.Structural dynamics (Melville, N.Y.) · 2023Article
- Core-Level Photoelectron Angular Distributions at the Liquid-Vapor Interface.Accounts of chemical research · 2023Article
- Absolute Electronic Energetics and Quantitative Work Functions of Liquids from Photoelectron Spectroscopy.Accounts of chemical research · 2023Article
- UV Photoelectron Spectroscopy of Aqueous Solutions.Accounts of chemical research · 2022Article
- Observation of a transient intermediate in the ultrafast relaxation dynamics of the excess electron in strong-field-ionized liquid water.Nature communications · 2022Article
- Accurate Vertical Ionization Energy of Water and Retrieval of True Ultraviolet Photoelectron Spectra of Aqueous Solutions.The journal of physical chemistry letters · 2022Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This perspective article reviews specific challenges associated with photoemission spectroscopy of bulk liquid water, aqueous solutions, water droplets and water clusters. The main focus lies on retrieving accurate energetics and photoelectron angular information from measured photoemission spectra, and on the question how these quantities differ in different aqueous environments. Measured photoelectron band shapes, vertical binding energies (ionization energies), and photoelectron angular distributions are influenced by various phenomena. We discuss the influences of multiple energy-dependent electron scattering in aqueous environments, and we discuss different energy referencing methods, including the application of a bias voltage to access absolute energetics of solvent and solute. Recommendations how to account for or minimize the influence of electron scattering are provided. The example of the hydrated electron in different aqueous environments illustrates how one can account for electron scattering, while reliable methods addressing parasitic potentials and proper energy referencing are demonstrated for ionization from the outermost valence orbital of neat liquid water.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.