Evidence map›Paper›PMID 35492804›Full record

ArticleRSC advances2021

Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

Alexander V Aksenov, Nicolai A Aksenov, Nikita K Kirilov, Anton A Skomorokhov, Dmitrii A Aksenov, Igor A Kurenkov, Elena A Sorokina, Mezvah A Nobi, Michael Rubin

Open access · goldAbstract read
In one paragraph

Article in RSC advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
1.1field-weighted citation impact, top 25% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 13 citations in OpenAlex.

  1. Article
  2. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 3 institutions in 2 countries.

Alexander V AksenovDepartment of Chemistry, North Caucasus Federal University 1a Pushkin St. Stavropol 355017 Russia aaksenov@ncfu.ru.ORCID https://orcid.org/0000-0002-6644-9949
Nicolai A AksenovDepartment of Chemistry, North Caucasus Federal University 1a Pushkin St. Stavropol 355017 Russia aaksenov@ncfu.ru.ORCID https://orcid.org/0000-0002-7125-9066
Nikita K KirilovDepartment of Chemistry, North Caucasus Federal University 1a Pushkin St. Stavropol 355017 Russia aaksenov@ncfu.ru.
Anton A SkomorokhovDepartment of Chemistry, North Caucasus Federal University 1a Pushkin St. Stavropol 355017 Russia aaksenov@ncfu.ru.
Dmitrii A AksenovDepartment of Chemistry, North Caucasus Federal University 1a Pushkin St. Stavropol 355017 Russia aaksenov@ncfu.ru.ORCID https://orcid.org/0000-0002-0727-9652
Igor A KurenkovDepartment of Chemistry, North Caucasus Federal University 1a Pushkin St. Stavropol 355017 Russia aaksenov@ncfu.ru.ORCID https://orcid.org/0000-0002-0911-4093
Elena A SorokinaOrganic Chemistry Department, Peoples' Friendship University of Russia (RUDN University) 6, Miklukho-Maklaya St. Moscow 117198 Russian Federation.ORCID https://orcid.org/0000-0001-8867-7988
Mezvah A NobiDepartment of Chemistry, University of Kansas 1567 Irving Hill Road Lawrence KS 66045 USA mrubin@ku.edu.
Michael RubinDepartment of Chemistry, North Caucasus Federal University 1a Pushkin St. Stavropol 355017 Russia aaksenov@ncfu.ru.ORCID https://orcid.org/0000-0002-1668-9311
North-Caucasus Federal University · RUUniversity of Kansas · USPeoples' Friendship University of Russia · RU

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The mechanistic rationale involving activation of nitroalkanes towards interaction with nucleophilic reagents in the presence of polyphosphoric acid (PPA) was re-evaluated. Could nitrile oxide moieties be formed during this process? This experiment demonstrates that at least in some cases this could happen, as generated nitrile oxides were successfully intercepted as adducts of [3 + 2] cycloadditions.

Identifiers

PMID35492804
PMCPMC9043268
OpenAlexW3213193302

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.