ArticleRSC advances2021
A library of new bifunctional alkenes obtained by a highly regiodivergent silylation of 1,5-hexadiene.
Article in RSC advances, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
An efficient methodology for the synthesis of two groups of silicon-containing alkenes is reported. It includes a highly regioselective functionalization of 1,5-hexadiene through hydrosilylation and dehydrogenative silylation with organofunctional silanes and siloxanes. The established conditions enable selective monofunctionalization of 1,5-hexadiene regardless of the organosilicon modifier used as well as the type of functional group bonded to the silicon-based compound. All products were isolated and fully characterized by NMR spectroscopy and MS techniques.
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