ArticleRapid communications in mass spectrometry : RCM2022
Detailed chemical analysis of a fully formulated oil using dielectric barrier discharge ionisation-mass spectrometry.
Article in Rapid communications in mass spectrometry : RCM, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed, 12 citations in OpenAlex.
- Adulteration Detection of Multi-Species Vegetable Oils in Camellia Oil Using SICRIT-HRMS and Machine Learning Methods.Foods (Basel, Switzerland) · 2026Article
- Chemical analysis of additives included in fully formulated oils using high-performance liquid chromatography-tandem mass spectrometry.Rapid communications in mass spectrometry : RCM · 2024Article
- Applications of ambient ionization mass spectrometry in 2022: An annual review.Analytical science advances · 2023Review
- Detailed chemical analysis of a fully formulated oil using dielectric barrier discharge ionisation-mass spectrometry.Rapid communications in mass spectrometry : RCM · 2022Article
- Ion Chemistry in Dielectric Barrier Discharge Ionization: Recent Advances in Direct Gas Phase Analyses.Mass spectrometry reviewsReview
- First 20 Years of Orbitrap Mass Spectrometry as the Mainstream Analytical Technique.Mass spectrometry reviewsReview
Corrections and comments
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
Abstract
rationaleFully formulated oils (FFOs) are integral to automotive lubrication; however, detailed compositional analysis is challenging due to high levels of chemical complexity. In particular, existing mass spectrometric approaches often target particular FFO components, leading to poor analytical coverage of the overall formulation, with increased overheads and analytical timescales.
methodsHerein we report the application of a commercially available SICRIT SC-20 dielectric barrier discharge ionisation (DBDI) source and Thermo Fisher Scientific LTQ Orbitrap XL to the analysis of an FFO. Nitrogen was used as a discharge gas for the DBDI source, and was modified using a range of commonplace solvents to tailor the experimental conditions for the analysis of various components.
resultsThe reported method allowed analysis of a range of FFO components of interest, encompassing a wide range of chemistries, in under 1 min. By modifying the discharge gas used for ionisation, experiments could be optimised for the analysis of particular FFO components across positive and negative ion modes. In particular, use of water vapour as a discharge gas modifier with positive ion mode mass spectrometry permitted concomitant analysis of antioxidants and base oil hydrocarbons. Furthermore, case studies of selected linear alkanes and alkenes profile the differences in the range of ions formed across these saturated and unsaturated aliphatic compounds, giving insight into the fate of base oil hydrocarbons in FFO analyses.
conclusionsA rapid method for analysis of FFO compositions has been developed and provides coverage of a range of components of interest. The results indicate that the method presented may be of utility in analysis of other FFOs or similarly challenging complex mixtures.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.