Mesoporous Carbon-Supported Pd Nanoparticles in the Metallic State-Catalyzed Acylation of Amides with Aryl Esters via C-O Activation.

Hui-Fang Huo, Dan Liu, Agula Bao, Tegshi Muschin, Chaolumen Bai, Yong-Sheng Bao

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Article in ACS omega, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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6 authors.

Hui-Fang HuoCollege of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University, Hohhot 010022, China.

Dan LiuCollege of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University, Hohhot 010022, China.

Agula BaoCollege of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University, Hohhot 010022, China.ORCID https://orcid.org/0000-0002-7859-9960

Tegshi MuschinCollege of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University, Hohhot 010022, China.ORCID https://orcid.org/0000-0002-1571-3738

Chaolumen BaiCollege of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University, Hohhot 010022, China.

Yong-Sheng BaoCollege of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University, Hohhot 010022, China.ORCID https://orcid.org/0000-0002-6686-7171

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Carbon, an abundant, inexpensive, and nonmetallic material, is an inimitable support in heterogeneous catalysis, and variable carbonaceous materials have been utilized to support metal nanoparticle catalysts. We developed an efficient and stable heterogeneous catalyst with highly dispersed metallic palladium nanoparticles embedded in an ordered pore channel of mesoporous carbon and first applied the catalyst to construct imides from amides using aryl esters as an acylation reagent via C-O activation. The catalyst represents excellent catalytic performance and could be reused and recycled five times without any significant decrease in activity. The heterogeneous nature of metallic state palladium was proven to be the active center in the acylation reaction.

Identifiers

PMID35474796

DOI10.1021/acsomega.1c07342

PMCPMC9026098

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