ArticleACS omega2022
Copper(I) Bis(diimine) Complexes with High Photooxidation Power: Reductive Quenching of the Excited State with a Benzimidazoline Sacrificial Donor.
Article in ACS omega, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- A donor-acceptor photosensitizer-catalyst dyad for light-driven nicotinamide hydrogenation.Chemical science · 2026Article
- Homomolecular Photon Upconversion in a Perylene-Decorated Iron(III) Complex.Journal of the American Chemical Society · 2025Article
- Visible Light-Driven Excited-State Copper-BINAP Catalysis for Accessing Diverse Chemical Reactions.Chem catalysis · 2024Article
- Photochemical charge accumulation in a heteroleptic copper(i)-anthraquinone molecular dyadChemical science · 2023Article
- Enabling artificial photosynthesis systems with molecular recycling: A review of photo- and electrochemical methods for regenerating organic sacrificial electron donors.Beilstein journal of organic chemistry · 2023Review
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The reductive quenching of photoexcited photosensitizers is a very efficient way to achieve challenging reduction reactions. In this process, the excited photosensitizer is reduced by a sacrificial electron donor. This mechanism is rarely observed with copper(I) bis(diimine) complexes, which are nevertheless acknowledged as very promising photosensitizers. This is due to the fact that they are very poor photooxidants and prove unable to react with common donors once promoted in their excited state. In this article, we evidence the rare reductive quenching cycle with two specially designed copper(I) complexes. These complexes exhibit improved photooxidation power thanks to an optimized coordination sphere made of strongly π-accepting ligands. Reductive quenching of the excited state of the latter complexes with a classical benzimidazoline sacrificial donor is monitored, and reduced complexes are accumulated during prolonged photolysis. Trials to utilize the photogenerated reductive power are presented.
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Registered trials
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