ArticleAngewandte Chemie (International ed. in English)2022
Growth of N-Heterocyclic Carbene Assemblies on Cu(100) and Cu(111): From Single Molecules to Magic-Number Islands.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Electrophilic activation of water by a carbene catalyzed by a copper surface.Chemical science · 2026Article
- Modulating CACS applied energy materials · 2025Article
- N-Heterocyclic Carbenes on a III-V Semiconductor: From Chain Formation to Ordered Monolayers.Angewandte Chemie (International ed. in English) · 2025Article
- Article
- Surface Characterization of N-Heterocyclic Carbenes on Gold and Silver: Exploring Distinct Crystalline Facets.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Writing with Molecules: Tip-Induced Local Chemisorption of N-Heterocyclic Olefins on Cu(111).Journal of the American Chemical Society · 2025Article
- N-Heterocyclic Carbene Monolayers on Metal-Oxide Films: Correlations between Adsorption Mode and Surface Functionality.Langmuir : the ACS journal of surfaces and colloids · 2024Article
- Enhanced catalytic activity of N-heterocyclic carbene stabilized surface adatoms for CO reduction reaction.Communications chemistry · 2023Article
- NHC stabilized copper nanoparticlesChemical communications (Cambridge, England) · 2023Article
- Stability of N-Heterocyclic Carbene Monolayers under Continuous Voltammetric Interrogation.ACS applied materials & interfaces · 2023Article
- N-Heterocyclic Carbenes: Molecular Porters of Surface Mounted Ru-Porphyrins.Angewandte Chemie (International ed. in English) · 2022Article
- Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface.Journal of the American Chemical Society · 2022Article
- Growth of N-Heterocyclic Carbene Assemblies on Cu(100) and Cu(111): From Single Molecules to Magic-Number Islands.Angewandte Chemie (International ed. in English) · 2022Article
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9 authors.
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Abstract
N-Heterocyclic carbenes (NHCs) have superior properties as building blocks of self-assembled monolayers (SAMs). Understanding the influence of the substrate in the molecular arrangement is a fundamental step before employing these ligands in technological applications. Herein, we study the molecular arrangement of a model NHC on Cu(100) and Cu(111). While mostly disordered phases appear on Cu(100), on Cu(111) well-defined structures are formed, evolving from magic-number islands to molecular ribbons with coverage. This work presents the first example of magic-number islands formed by NHC assemblies on flat surfaces. Diffusion and commensurability are key factors explaining the observed arrangements. These results shed light on the molecule-substrate interaction and open the possibility of tuning nanopatterned structures based on NHC assemblies.
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